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Volumn 16, Issue 7, 1997, Pages 1193-1199

Synthesis and structural characterization of Zintl anions containing the tris(ethylenediamine)-zinc cation: [Zn(N2C2H8)3] [Te3]·(0.5en) and [Zn(N2C2H8)3]2[Sn 2Te6]·(en)

Author keywords

Crystal structure; Electrochemical synthesis; Tellurium; Tin; Zinc; Zintl anion

Indexed keywords


EID: 0000406548     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(96)00367-1     Document Type: Article
Times cited : (46)

References (63)
  • 32
    • 0040124190 scopus 로고
    • Rings, Clusters and Polymers of the Main Group Elements
    • ed. A. Cowley. ACS, Washington, DC
    • (l) Corbett, J. D., Critchlow, S. C. and Burns, R. C., Rings, Clusters and Polymers of the Main Group Elements, ed. A. Cowley. ACS Symposium Series 232. ACS, Washington, DC, 1983, pp. 95-110, and refs therein.
    • (1983) ACS Symposium Series 232 , pp. 95-110
    • Corbett, J.D.1    Critchlow, S.C.2    Burns, R.C.3
  • 40
    • 85033523549 scopus 로고
    • Ph.D. Dissertation, Princeton University, June
    • (c) Warren, C. J., Ph.D. Dissertation, Princeton University, June 1994;
    • (1994)
    • Warren, C.J.1
  • 47
    • 85033511095 scopus 로고    scopus 로고
    • note
    • - passed = 12%. The deep purple color of the solution suggests that some fraction of the polyanions produced are soluble and remain in solution. Qualitative microprobe analysis (Princeton Gamma Technology EDS detector on a Hitachi S-2700 SEM) confirmed the crystals contained Zn and Te in approximately 1:3 ratio.
  • 49
    • 85033543427 scopus 로고    scopus 로고
    • note
    • 6]·(en) (2) also produces a mixture of other products from which single crystals of 2 had to be mechanically separated to determine the overall yield. A yield of 41.6% was based on 0.0412 g of 2 and was calculated on the basis of moles of Sn.
  • 53
    • 0001647167 scopus 로고
    • eds G. M. Sheldrick, C. Kruger and R. Goddard. Oxford University Press, Oxford
    • SHELX86 : Sheldrick, G. M., in Crystallographic Computing 3, eds G. M. Sheldrick, C. Kruger and R. Goddard. Oxford University Press, Oxford, 1985, pp. 175-189.
    • (1985) Crystallographic Computing 3 , pp. 175-189
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.