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27c supporting our assumption of diffusion-controlled quenching
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27c supporting our assumption of diffusion-controlled quenching.
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Tetraethylammonium cyanide was tested as well, but problems arose with the necessary removal of the salt before GC analysis
-
(c) Tetraethylammonium cyanide was tested as well, but problems arose with the necessary removal of the salt before GC analysis.
-
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50
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11744261218
-
-
note
-
This method of measuring IEs is both quantitatively superior to and significantly faster and cheaper than analysis by GC/MS.
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51
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33751385206
-
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The choice of 1,3,5-tri-tert-butylbenzene was based on the condition that it absorbs >99% of the incoming light, that its radical cation can oxidize naphthalene (the oxidation potentials of naphthalene and 1,3.5-tri-tert-butylbenzene are 1.60 and 2.01 V, respectively), and that the bulky substituent will decrease the rate of back electron transfer. See: Gould, I. R.; Farid, S. J. Phys. Chem. 1993, 97, 13067-13072.
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11744261219
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note
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Evidence for the existence of 1:2 complexes of tetracyanoethene and naphthalene under conditions with a high naphthalene/tetracyanoethene ratio has recently been presented in ref 25.
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8 L/mol s (ref 11).
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74
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0142037811
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A normal equilibrium isotope effect on the electron transfer between an organic radical cation and its neutral parent has recently also been observed for thianthrene: (a) Liu, Z.-L.; Lu, J.-M.; Chen, P.; Wang, X.-L.; Wen, X.-L.; Yang, L.; Liu, Y.-C. J. Chem. Soc., Chem. Commun. 1992, 76-77. (b) Wen, X.-L.; Liu, Z.-L.; Lu, J.-M.; Liu, Y.-C. J. Chem. Soc., Faraday Trans. 1992, 88, 3323-3326.
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A normal equilibrium isotope effect on the electron transfer between an organic radical cation and its neutral parent has recently also been observed for thianthrene: (a) Liu, Z.-L.; Lu, J.-M.; Chen, P.; Wang, X.-L.; Wen, X.-L.; Yang, L.; Liu, Y.-C. J. Chem. Soc., Chem. Commun. 1992, 76-77. (b) Wen, X.-L.; Liu, Z.-L.; Lu, J.-M.; Liu, Y.-C. J. Chem. Soc., Faraday Trans. 1992, 88, 3323-3326.
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11644283035
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Attack on the radical cation by the nucleophile in the solvent cage was also proposed by Lemmetyinen and co-workers for the photoamination of phenanthrene in the presence of DCB, on the basis of flash photolysis data: Nieminen, K.; Niiranen, J.; Lemmetyinen, H.; Sychtchikova, I. J. Photochem. Photobiol., A 1991, 61, 235-243.
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11744278214
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This suggests that the diffusing apart of 1,3,5-tri-tert-butylbenzene radical cation and DCB radical anion is more effective than in the corresponding case of naphthalene radical cations; cf. ref 33.
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