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59 and van der Waals interaction, especially between the C17-long chains, may mainly stabilize the whole aggregate particle, though the hydrogen bonding can maintain the local structure of the macrocycle array. This should be distinguished from the role of water (or alcohol) molecules in the folding of the covalently linked Chl dimers in nonpolar solvents: hydrogen bonding must at any cost draw a macrocycle aside the other one. Our view is also supported by the finding that the carbonyl stretching region of the IR spectrum of the Chl a′ aggregate precipitate did not change upon exposure to water vapor.
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