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Selective excitation also does not occur because the Q bands are built on a broad background that appears to be a tail of the Soret band. Such a tail appears to be present in a variety of porphyrin dimers. (See ref 21b and Yan, X.; Holten, D. J. Phys. Chem. 1988, 92, 409–414.) Since the Soret involves strongly coupled transitions of the two monomeric subunits, excitation into a tall of the Soret is likely to yield excitations on either the Zn or H2 subunit after internal conversion from the Soret to the Q, or lowest 1(π, π*), manifold. In keeping with this, shifting the wavelength of the 350-fs excitation pulse to 620 nm (to the red of the Q(0,0) band of the Zn subunit) still results in bleaching in the Q bands of both subunits.
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Warshel, A.1
Chu, Z.T.2
Parson, W.W.3
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79
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Kirmaier, C.; Molten, D.; Parson, W. W. Biochim. Biophys. Acta 1985, 810, 33–48.
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Kirmaier, C.1
Molten, D.2
Parson, W.W.3
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82
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85023316950
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See also ref 4c. in press.
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See also ref 4c. Kirmaier, C.; Gaul, D.; Debey, R.; Molten, D.; Schenck, C. C. Science, in press.
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Science
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Kirmaier, C.1
Gaul, D.2
Debey, R.3
Molten, D.4
Schenck, C.C.5
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83
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85023366984
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Temperature-insensitive electron transfer in the bacterial reaction center is discussed in refs 2a,b,e,4c,25,26b, and 27.
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Temperature-insensitive electron transfer in the bacterial reaction center is discussed in refs 2a,b,e,4c,25,26b, and 27.
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