A new protocol for the acetoxyallylation of aldehydes mediated by indium in THF

Organic Letters

Volumn 3, Issue 19, 2001, Pages 2981-2983

  Lombardo, Marco ^a   Girotti, Rugiada ^a   Morganti, Stefano ^a   Trombini, Claudio ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

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EID: 0000382683     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol016315g     Document Type: Article

References (33)

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30. Typical Procedure. To a suspension of indium powder (0.115 g, 1 mmol) in THF (1 mL) was added 1-acetoxy-3-bromo-1-propene 3 (0.175 mL, 1.5 mmol) at 0°C. The heterogeneous mixture was stirred for 30 min at 0°C, the ice bath was removed, and stirring was continued for 3.5 h at room temperature. The aldehyde was added (1 mmol) at 0°C, and the reaction mixture was stirred for 4 h at 0°C.
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