Metal-Metal Multiply-Bonded Complexes of Technetium. 3.1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal-Metal Bond Order of 3.5

Inorganic Chemistry

Volumn 35, Issue 7, 1996, Pages 1831-1838

  Cotton, F Albert ^b   Haefner, Steven C ^a,b   Sattelberger, Alfred P ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000374356     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9508583     Document Type: Article

References (34)

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2. (b) Part 2: Bryan, J. C.;Cotton, F. A., Daniels, L. M; Haefner, S. C., Sattelberger, A. P. Inorg. Chem. 1995, 34, 1875.
3. Cotton, F. A.;Walton, R. A. Multiple Bonds Between Metal Atoms, 2nd ed.;Oxford University Press: New York, 1993. and references cited therein.
4. Spitsyn, V. I.;Kuzina, A. F.;Oblova, A. A.;Kryuchkov, S. V. Russ. Chem. Rev. (Engl Transl.) 1985, 54, 373.
5. Baldas, J Adv. Inorg. Chem. 1994, 41, 1.
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7. Libson, K.;Barnett, B. L.;Deutsch, E. Inorg. Chem. 1983, 22, 1695.
8. Hendrickson, D. N.;Sohn, Y. S.;Gray, H. B. Inorg. Chem. 1971, 10, 1559
9. (a) Bino, A., Cotton, F. A.;Fanwick, P. E. Inorg. Chem. 1979, 18, 3558.
10. (b) Cotton, F. A.;Frenz, B. A.;Deganello, G.;Shaver, A. J. Organomet. Chem. 1979, 50, 227.
11. Sheldrick, G. M. SHELXL-93; Institut fur Anorganische Chemie der Universität Göttingen, Göttingen, FRG, 1993.
12. Sheldrick, G. M SHELXS-S6; Institut für Anorganische Chemie der Universität Göttingen, Göttingen, FRG, 1986.
13. -1/4; k = overall scale factor.
14. Flack. H. D. Acta Crystallogr. 1983, A37, 22.
15. 2 are statistically about twice as large as those based on F, and an R-index based on all data is inevitably larger than one based only on data with F greater than a given threshold.
16. (a) Brant, P.;Salmon, D. J.;Walton, R. A. J. Am. Chem. Soc 1978, 100, 4424.
17. (b) Dunbar, K. R., Walton, R. A. Inorg. Chem. 1985, 24, 5.
18. (a) Ebner, J. R.;Walton, R. A. Inorg. Chim. Acta 1975, 14, L45.
19. (b) Cotton, F. A.;Fanwick, P. E.;Gage, L. D.;Kalbacher, B.;Martin, D. S. J. Am. Chem Soc 1977, 99, 5642.
20. Bursten, B. E., Cotton, F. A., Fanwick, P. E.;Stanley, G. G.;Walton, R. A. J. Am. Chem. Soc. 1983, 105, 2606.
21. See: Reference 3; p 739.
22. See: Reference 3; pp 701-702.
23. Cotton, F. A.;Pedersen, E. J. Am. Chem. Soc. 1975, 97, 303.
24. Cotton, F. A.;Pedersen, E. Inorg. Chem 1975, 14, 383.
25. Cotton, F. A.;Dunbar, K. R.;Falvello, L. R.;Tomas, M.;Wallon, R. A. J. Am. Chem. Soc. 1983, 105, 4950.
26. (a) Cotton, F. A.;Daniels, L.;Davison, A; Orvig, C. Inorg. Chem. 1981, 20, 3051.
27. (b) Cotton, F. A.;Davison, A., Day, V. W.;Fredrich, M. F.;Orvig, C.;Swanson, R. Inorg. Chem. 1982, 27, 1211.
28. 2 units has been shown to influence the orientation of the M-M bond within the quasi-cube of ligands. Cotton, F. A.;Matonic, M. H.;Silva, D. O. Inorg. Chim. Acta 1995, 234, 115.
29. (a) Cotton, F. A.;Vidyasagar, K. Inorg. Chim. Acta 1989, 166, 105.
30. (b) Cotton, F. A.;Diebold, M P.;Roth, W. J. Inorg. Chim. Acta 1988, 144, 17.
31. (c) Ferry, J.;Gallagher, J.;Cunningham, D.;McArdle, P. Inorg. Chim. Acta 1989, 164, 185.
32. (d) Ferry, J.;Gallagher, J.;Cunningham, D.;McArdle, P. Inorg. Chim. Acta 1990, 172, 79.
33. Cotton, F. A., Price, A.;Vidyasagar, K. Inorg. Chem. 1990, 29, 5143.
34. Cotton, F. A.;Dikarev, E. V. Inorg. Chem. 1995, 34, 3809.