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[6c] For a photochemical approach to silanediyl 2, see: R. Corriu, G. Laneau, C. Priou, F. Soulairol, N. Auner, R. Probst, R. Conlin, C. Tan, J. Organomet. Chem. 1994. 466, 55-68.
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0001771496
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[81 [8a] Isocyanates and isothiocyanates serve as oxygen or sulfur transfer reagents towards diaminosilanes: R. J. P. Corriu, G. F. Lanneau, V. D. Mehta, J. Organomet. Chem. 1991, 419, 9-26.
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[8b] Transfer of sulfur from isothiocyanate to decamethylsilicocene has been reported: P. Jutzi, A. Möhrke, Angew. Chem. 1989, 101, 769-770;
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Jutzi, P.1
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19
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33745342807
-
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note
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1J14N = 6 Hz) as well as by comparison with an authentic sample.
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20
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26544448273
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P. Arya, J. Boyer, R. J. P. Corriu, G. F. Lanneau, M. Perrot, J. Organomet. Chem. 1988, 346, C11-14.
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[11a] H. B. Yokelson. A. J. Millevolte, B. R. Adams, R. West, J. Am. Chem. Soc. 1987, 109, 4116-4118.
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[11b] K. L. McKillop, G. P. Gillette, D. R. Powell, R. West, J. Am. Chem. Soc. 1992, 114, 5203-5208.
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B. J. Hclmer, R. West, R. J. P. Corriu, M. Poirier, G. Royo, A. de Saxcè, J. Organomet. Chem. 1983, 251, 295-298.
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24
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33745367596
-
-
Further details of the crystal structure investigation are available from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshaffen (Germany), on quoting the depository number CSD-404128
-
Further details of the crystal structure investigation are available from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshaffen (Germany), on quoting the depository number CSD-404128.
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-
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26
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0008673263
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For a discussion of the electronic situation in 1,3-disiladioxetanes, see: [15a] M. S. Gordon. T. J. Packwood, M. T. Carroll, J. O. Boatz, J. Phys. Chem. 1991, 95, 4332-4337.
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2 ring systems of higher group 14 homologs, see: M. Lappert, Main Group Metal Chemistry 1994, 17, 183-207 and references cited therein.
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33845378666
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[20b] For a theoretical study of the dimerization of silanones, see: T. Kudo, S. Nagase, J. Am. Chem. Soc. 1985, 107, 2589-2595.
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40
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33745347544
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paper to be published
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[22b] The addition of 2 to adarnantanone yields the corresponding stable siloxirane: J. Belzner, H. Ihmels, paper to be published.
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Belzner, J.1
Ihmels, H.2
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0039246503
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[23a] For the nucleophilic addition of stable tin(II) amides to acid chlorides, see: M. F. Lappert, M. C. Misra, M. Onyszchuk, R. S. Rowe. P. P. Power, M. J. Slade, J. Organomet. Chem. 1987, 330, 31-46.
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42
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33745346970
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unpublished results
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[23b] 2 acts towards alkynes as a nucleophile: J. Belzner, H. Ihmels, unpublished results.
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Belzner, J.1
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J. E. Baldwin, A. E. Derome, P. D. Riordan, Tetrahedron 1983, 39, 2989-2994.
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44
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33745344239
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[27a].
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45
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[27a] P. Arya, J. Boyer, F. Carre, R. Corriu, G. Lanneau, J. Lapasset, M. Perrot, C. Priou, Angew. Chem. 1989, 101, 1069-1071;
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Arya, P.1
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48
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21344491344
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[27b] For double bonds of sulfur to higher homologs of group 14, see: N. Tokitoh, Y. Matsuhashi, K. Shibata, T. Matsumoto, H. Suzuki, M. Saito, K. Manmaru, R. Okazaki, Main Group Metal Chemistry 1994, 17, 55-65.
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J. Belzner, D. Schär, B. O. Kneisel, R. Herbst-Irmer, Organometallics 1995, 14, 1840-1843.
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50
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33745334151
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[7]
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[7].
-
-
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51
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21344487523
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The hydrolysis of this dichlorosilane. yielding an HCl adduct of 12, was investigated independently by Auner: N. Auner, R. Probst, C.-R. Heikenwälder, E. Herdtweck, S. Gamper, G. Müller, Z. Naturforsch., B: Chem. Sci. 1993, 48, 1625-1634.
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52
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0000613655
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Also attempts to dehydrate teiramesityldisiloxanediol with dicyclohexylcarbodiimide to the corresponding cyclodisiloxane 4b failed: M. J. Michalczyk, M. J. Fink, K. J. Haller, R. West, J. Michl, Orsanometallics 1986, 5, 531-538.
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Michalczyk, M.J.1
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