Three dinuclear copper(II) carboxylates with the paddle-wheel cage structure as intermediates in copper(II) catalyzed oxidations of carboxylic acids. X-ray crystal structures of [tetrakis(diphenyl acetato-μ-O,O′)bis(acetonitrile-N)dicopper(II)] tetrakis(acetonitrile), [tetrakis(diphenylacetato-μ-O,O′)bis(acetone-O)dicopper(II)].

Inorganica Chimica Acta

Volumn 267, Issue 2, 1998, Pages 183-192

  Agterberg, F P W ^a,b   Provo Kluit H A J ^a   Driessen, W L ^a   Reedijk, J ^a   Oevering, H ^b   Buijs, W ^b   Veldman, N ^c   Lakin, M T ^c   Spek, A L ^c  

^a LEIDEN UNIVERSITY   (Netherlands)

^b DSM RESEARCH   (Netherlands)

^c UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Carboxylate complexes; Catalysis; Copper complexes; Crystal structures; Dinuclear complexes; Oxidation

Indexed keywords

ACETONE; ACETONITRILE; CARBOXYLATION; CATALYSIS; CRYSTAL STRUCTURE; CRYSTALS; ETHANOL; HYDROGEN BONDS; OXIDATION; WHEELS;

CARBOXYLATE COMPLEXES; COPPER COMPLEXES; DINUCLEAR COMPLEX; SQUARE-PYRAMIDAL GEOMETRY; STRUCTURAL CHARACTERIZATION; TRICLINIC SPACE GROUP; X RAY CRYSTAL STRUCTURES; ZERO-FIELD SPLITTINGS;

COPPER COMPOUNDS;

EID: 0000363290     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05579-5     Document Type: Article

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