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Tetrahedron Letters

Volumn 25, Issue 20, 1984, Pages 2151-2154

Regioselective stannylmetalation of acetylenes in the presence of transition-metal catalyst

(5) Hibino, Jun ichi a Matsubara, Seijiro a Morizawa, Yoshitomi a Oshima, Koichiro a Nozaki, Hitosi a

a KYOTO UNIVERSITY (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000363193 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(01)81185-0 Document Type: Article

Times cited : (87)

References (21)

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2
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- For the reaction with allenes, see Y. Morizawa, H. Oda, K. Oshima, H. Nozaki, Tetrahedron Lett., in press.

3
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- Regioselective addition of trimethylstannylcopper?dimethyl sulphide to 1-alkynes: synthesis of ?-substituted 2-(trimethylstannyl)-1-alkenes
- Piers and his coworkers have showed that trimethylstannylcopper-dimethyl sulfide complex adds to triple bond. The reaction requires coexisting of proton donor such as methanol
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- Piers¹ Chong²

4
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- Synthesis and transmetalation of alkyl (E)-2,3-bis(trimethylstannyl)-2-alkenoates, novel organotin compounds
- 2Zn in this work reacts without proton donor and various functionalized vinylstannanes could be prepared as shown in Scheme 2.
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- Piers¹ Chong²

5
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6
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7
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8
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- 3SnMgR' see
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9
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13
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15
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- After adding 4-benzyloxy-1-butyne to the reagent, the reaction mixture was cooled to −78°C and stirred for 1 min. Benzaldehyde (3 mol equivalent) was added in one portion.

16
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- ALKYLATION, ARYLATION, AND VINYLATION OF ACYL CHLORIDES BY MEANS OF ORGANOTIN COMPOUNDS IN THE PRESENCE OF CATALYTIC AMOUNTS OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(O)
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17
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21
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- 22O: C, 85.65; H, 8.34%.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.