Nitrogen- Vs Carbon-Coordination of the α-Cyano-Stabilized Phosphorus Ylide Ph3P=C(H)CN, X-ray Crystal Structure of {Pd(dmba)[P(OMe)3] [N≡C - C(H)=PPh3]}(ClO4)

Inorganic Chemistry

Volumn 36, Issue 6, 1997, Pages 1136-1142

  Falvello, Larry R ^a   Fernández, Susana ^a   Navarro, Rafael ^a   Urriolabeitia, Esteban P ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000358598     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960904e     Document Type: Article

References (43)

1. Johnson, A. W.; Kaska, W. C.; Starzewski, K. A. O.; Dixon, D. A. Ylides and Imines of Phosphorus: John Wiley & Sons, Inc.: New York, 1993; Chapter 14 and references given therein.
2. (a) Burmeister, J. L.; Silver, J. L.; Weleski, E. T.; Schweizer, E. E.; Kopay, C. M. Synth. React. Inorg. Met.-Org. Chem. 1973, 3, 339.
3. (b) Nishiyama, H.; Itoh, K.; Ishii, Y. J. Organomet. Chem. 1975, 87, 129.
4. (c) Weleski, E. T.; Silver, J. L.; Jansson, M. D.; Burmeister, J. L. J. Organomet. Chem. 1975, 102, 365.
5. (a) Trippett, S.; Walker, D. M. J. Chem. Soc. 1959, 3874.
6. (b) Pappas, J. J.; Gancher, E. J. Org. Chem. 1966, 1287.
7. (c) Pappas, J. J.; Gancher, E. J. Org. Chem. 1966, 3877.
8. (d) Bestmann, H. J.; Schmidt, M. Tetrahedron Lett. 1987, 28, 2111.
9. (e) Bestmann, H. J.; Schmidt, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 79.
10. (f) Pandolfo, L.; Facchin, G.; Bertani, R.; Ganis, P.; Valle, G. Angew. Chem., Int. Ed. Engl. 1994, 33, 576.
11. Falvello, L. R.; Fernández, S.; Navarro, R.; Urriolabeitia, E. P. Inorg. Chem. 1996, 35, 3064 and references given therein.
12. Clark, H. C.; Manzer, L. E. Inorg. Chem. 1971, 10, 2699.
13. Storhoff, B. N.; Lewis, H. C. Coord. Chem. Rev. 1977, 23, 1.
14. Wada, M.; Shimohigashi, T. Inorg. Chem. 1976, 15, 954.
15. Bestmann, H. J.; Snyder, J. P. J. Am. Chem. Soc. 1967, 89, 3936.
16. Deeming, A. J.; Rothwell, I. P.; Hursthouse, M. B.; New, L. J. Chem. Soc., Dalton Trans, 1978, 1490.
17. Braunstein, P.; Matt, D.; Dusausoy, Y.; Fischer, J.; Mitschler, A.; Ricard, L. J. Am. Chem. Soc. 1981, 103, 5115.
18. Braunstein, P.; Matt, D.; Dusausoy, Y.; Fischer, J. Organometallics 1983, 2, 1410.
19. Bao, Q.-B.; Geib, S. J.; Rheingold, A. L.; Brill, T. B. Inorg. Chem. 1987, 26, 3453.
20. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans, 1989, S1.
21. Olmstead, M. M.; Guimerans, R. R.; Farr, J. P.; Balch, A. L. Inorg. Chim. Acta 1983, 75, 199.
22. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R. J. Chem. Soc., Perkin Trans, 2 1987, S1.
23. Kalyanasundari, M.; Panchanatheswaran, K.; Parthasarathi, V.; Robinson, W. T.; Wen, H. Acta Crystallogr. 1994, C50, 1738.
24. Schmidbaur, H.; Jeong, J.; Schier, A.; Graf, W.; Wilkinson, D. L.; Müller, G.; Krüger, C. New J. Chem. 1989, 13, 341.
25. 4) in which the ylide acts selectively as an O-donor ligand. Falvello, L. R.; Fernández, S.; Navarro, R.; Pascual, I.; Urriolabeitia, E. P. J. Chem. Soc., Dalton Trans., in press.
26. Davies, J. A.; Hartley, F. R. Chem. Rev. 1981, 81, 79.
27. Pearson, R. G. Inorg. Chem. 1973, 12, 712
28. (a) Pfeffer, M.; Grandjean, D.; Le Borgne, G. Inorg. Chem. 1981, 20, 4426.
29. (b) Dehand, J.; Jordanov, J.; Pfeffer, M.; Zinsius, M. C. R. Acad. Sci. Paris. Ser. C 1975, 281, 651.
30. (c) Vicente, J.; Areas, A.; Bautista, D.; Tiripicchio, A.; Tiripicchio Camellini, M. New J. Chem. 1996, 20, 345 and references given therein.
31. P-C = 52.0 Hz).
32. Clark, G. R.; Palenick, G. J. Inorg. Chem. 1970, 9, 2754.
33. Rosenthal, M. R. J. Chem. Educ. 1973, 50, 331.
34. Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed.; Wiley: New York, 1978; pp 242-243.
35. Usón, R.; Forniés, J.; Martínez, F. J. Organomet. Chem. 1976, 112, 105.
36. J. Chem. Educ. 1973, 50, A335.
37. Cope, A. C.; Friedrich, E. C. J. Am. Chem. Soc. 1968, 90, 909.
38. Forniés, J.; Navarro, R.; Sicilia, V. Polyhedron 1988, 7, 2659.
39. Sheldrick, G. M., SHELXS-86, Acta Crystallogr. 1990, A46, 467.
40. Sheldrick, G. M., SHELXL-93: FORTRAN program for the refinement of crystal structures from diffraction data. Göttingen University, 1993.
41. (a) Crystallographic calculations were done on a Local Area VAX-Cluster (VAX/VMS V5.5-2).
42. (b) Data reduction was done by the program XCAD4B: Harms, K. Private communication, 1995.
43. (c) Absorption corrections and molecular graphics were done using the commercial package: SHELXTL-PLUS, Release 4.21/V; Siemens Analytical X-ray Instruments, Inc., Madison, WI, 1990.