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Volumn 37, Issue 19, 1998, Pages 4979-4985

Molecular Rhenium(V) Oxotransferases: Oxidation of Thiols to Disulfides with Sulfoxides. The Case of Substrate-Inhibited Catalysis

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Indexed keywords


EID: 0000353390     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980348j     Document Type: Article
Times cited : (67)

References (54)
  • 30
    • 1842773748 scopus 로고    scopus 로고
    • The -SH chemical shift moves upfield: δ 1.4 (t, free) and 1.2 (t, coordinated)
    • The -SH chemical shift moves upfield: δ 1.4 (t, free) and 1.2 (t, coordinated).
  • 32
    • 85087582204 scopus 로고    scopus 로고
    • note
    • 6.
  • 37
    • 85087579788 scopus 로고    scopus 로고
    • note
    • 3 at 22 °C.
  • 39
    • 85087581406 scopus 로고    scopus 로고
    • -1: 968 (Re=O); 908 and 894 sh (S-O)
    • -1: 968 (Re=O); 908 and 894 sh (S-O).
  • 50
    • 1842673019 scopus 로고
    • Patti, S., Rappoport, Z., Stirling, C., Eds.; John Wiley & Sons: New York
    • We used as much as a 20× excess of styrene:thiol without success. This is not surprising since sulfenic acid has never been trapped before in the presence of thiol; usually sulfenic acid is generated thermally from sulfoxides. See for example: Drabowicz, J.; Kielbasinski, P.; Mikolajczyk, M. In The Chemistry of sulphones and sulphoxides; Patti, S., Rappoport, Z., Stirling, C., Eds.; John Wiley & Sons: New York, 1988; pp 268-270.
    • (1988) The Chemistry of Sulphones and Sulphoxides , pp. 268-270
    • Drabowicz, J.1    Kielbasinski, P.2    Mikolajczyk, M.3
  • 51
    • 0000811414 scopus 로고
    • It has been shown that ruthenium(IV) oxo complexes with bound phosphine oxidize free phosphine in solution rather than bound phosphine. See for example: Marmion, M. E.; Takeuchi, K. J. J. Am. Chem. Soc. 1986, 108, 510.
    • (1986) J. Am. Chem. Soc. , vol.108 , pp. 510
    • Marmion, M.E.1    Takeuchi, K.J.2
  • 54
    • 85087581083 scopus 로고    scopus 로고
    • note
    • 2OH.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.