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The -SH chemical shift moves upfield: δ 1.4 (t, free) and 1.2 (t, coordinated)
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3 at 22 °C.
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39
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85087581406
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-1: 968 (Re=O); 908 and 894 sh (S-O)
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We used as much as a 20× excess of styrene:thiol without success. This is not surprising since sulfenic acid has never been trapped before in the presence of thiol; usually sulfenic acid is generated thermally from sulfoxides. See for example: Drabowicz, J.; Kielbasinski, P.; Mikolajczyk, M. In The Chemistry of sulphones and sulphoxides; Patti, S., Rappoport, Z., Stirling, C., Eds.; John Wiley & Sons: New York, 1988; pp 268-270.
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85087581083
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note
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2OH.
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