Total Syntheses of the Cytotoxic Marine Natural Product, Aplysiapyranoid C

Journal of Organic Chemistry

Volumn 63, Issue 9, 1998, Pages 2982-2987

  Jung, Michael E ^a   Fahr, Bruce T ^a   D'Amico, Derin C ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000346999     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo972228j     Document Type: Article

References (21)

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18. 12
19. When less pyridine is used for the desilylation, the quaternary fluoride, formed by Markovnikov addition of HF to the trisubstituted alkene, is produced.
20. The Takai reaction on several aldehydes, e.g., benzaldehyde, dodecanal, and 2-(decyloxy)-2-methylpropanal, gave only chlorovinylation with no dechlorinated product observed.
21. We thank Dr. Darko Kantoci of Loma Linda University for his assistance is this separation.