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Volumn 42, Issue 16, 1986, Pages 4427-4436

Transition-metal catalyzed silylzincation and silylalumination of acetylenic compounds

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EID: 0000335563     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)87282-3     Document Type: Article
Times cited : (59)

References (24)
  • 6
    • 84918139770 scopus 로고    scopus 로고
    • a, M. Isobe, S. Kondo, N. Nagasawa, T. Goto, Chem. Lett., 1977, 679.
  • 7
    • 46049093325 scopus 로고
    • Enantioselektive 1,2-Additionen von Li-, Mg-, Zn- und Cu-organischen Verbindungen und von Li-Enolaten an Carbonylverbindungen im chiralen Medium DDB
    • (1979) Helvetica Chimica Acta , vol.62 , pp. 1701
    • Seebach1    Langer2
  • 8
    • 0000821699 scopus 로고
    • Enantioselektive 1,4-Additionen von metallorganischen Verbindungen an konjugierte Systeme im chiralen Medium DDB
    • (1979) Helvetica Chimica Acta , vol.62 , pp. 1710
    • Seebach1    Langer2
  • 10
    • 84918139769 scopus 로고    scopus 로고
    • a, M. Isobe, S. Kondo, N. Nagasawa, T. Goto, Chem. Lett., 1977, 679.
  • 12
    • 84918139768 scopus 로고    scopus 로고
    • 2SiLi provided l-dimethylphenylsilyl-2-cyclohexen-1-ol (60% yield) as the main product. See ref. 4d.
  • 13
    • 84918139767 scopus 로고    scopus 로고
    • 2 was also effective catalyst for silylzinc reagent, but not for silylaluminium reagent.
  • 16
    • 84918139766 scopus 로고    scopus 로고
    • 3 in situ and used directly without further purification.
  • 18
    • 84918139765 scopus 로고    scopus 로고
    • 10 provided (E)-3-trimethylsilyl-2-propen-1-ol and (E)-4-trimethylsilyl-3-buten-1-ol, respectively.
  • 19
    • 84918139764 scopus 로고    scopus 로고
    • 5-Trimethylsilyl-4-pentyn-1-ol gave the ordinal cis addition product (Table 3, entry 8).
  • 24
    • 84918139763 scopus 로고    scopus 로고
    • Financial support by the Ministry of Education, Science, and Culture, Japanese Government (Grant-in-Aid for Special Project Research No.59104005 60219015, and 61225011) is acknowledged.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.