Kinetics and mechanism of CCU photoreductive degradation on TiOi: The role of trichloromethyl radical and dichlorocarbene

Journal of Physical Chemistry

Volumn 100, Issue 6, 1996, Pages 2161-2169

  Choi, Wonyong ^a   Hoffmann, Michael R ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000333841     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp951431k     Document Type: Article

References (45)

1. (a) Fujishima, A.; Honda, K. Nature 1972, 238, 37.
2. (b) Grätzel, M. Ace. Chem. Res. 1981, 14, 376.
3. Fox, M. A. Ace. Chem. Res. 1983, 16, 314.
4. (a) Borgarello, E.; Serpone, N.; Emo, G.; Harris, R.; Pelizzetti, E.; Minero, C. Inorg. Chem. 1986, 25, 4499.
5. (b) Foster, N. S.; Noble, R. D.; Koval, C. A. Environ. Sci. Technol. 1993, 27, 350.
6. (a) Ollis, D. F., AI-Ekabi, H., Eds. Photocatalytlc Purification and Treatment of Water and Air; Elsevier: Amsterdam, 1993.
7. (b) Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann, D. W. Chem. Rev. 1995, 95, 69.
8. Frank, S. N.; Bard, A. J. J. Phys. Chem. 1977, 81, 1484.
9. (a) Choi, W.; Termin, A.; Hoffmann, M. R. Angew. Chem., Int. Ed. Engl. 1994, 33, 1091.
10. (b) Choi, W.; Termin, A.; Hoffmann, M. R. J. Phys. Chem. 1994, 98, 13669.
11. (a) Bahnemann, D. W.; Mönig, J.; Chapman, R. J. Phys. Chem. 1987, 91, 3782.
12. (b) Hilgendorff, M.; Hilgendorff, M.; Bahnemann, D. W. In Environmental Aspects of Electrochemistry and Photoelectrochemistry; Tomkiewicz, M., Haynes, R., Yoneyama, H., Hori, Y., Eds.; The Electrochemical Society: Pennington, NJ, 1993; pp 112-121.
13. Chemseddine, A.; Boehm, H. P. J. Mol. Catal. 1990, 60, 295.
14. Filby, W. G.; Mintas, M.; Giisten, H. Ber. Bunsen-Ges. Phys. Chem. 1981, 85, 189.
15. Moser, J.; Grätzel, M. J. Am. Chem. Soc. 1983, 705, 6547.
16. (a) Asmus, K.-D.; Bahnemann, D.; Krischer, K.; Lal, M.; Mönig, J. Life Chem. Rep. 1985, 3, 1.
17. (b) Mönig, J.; Bahnemann, D.; Asmus, K.D. Chem.-Biol. Interact. 1983, 45, 15.
18. Röster, R.; Asmus, K.-D. Z Naturforsch 1971, 26b, 1104.
19. (a) Bhatnagar, A.; Cheung, H. M. Environ. Sci. Technol. 1994,28, 1481.
20. (b) Hua, L; Hoffmann, M. R. Environ. Sci. Technol., in press.
21. Criddle, C. S.; McCarty, P. L. Environ. Sci. Technol. 1991, 25, 973.
22. (a) Lambert, F. L.; Hasslinger, B. L.; Franz, R. N., III. J. Electrochem. Soc.: Electrochem. Sci. Technol. 1975, 722, 737.
23. (b) Wawzonek, S.; Duty, R. C. J. Electrochem. Soc. 1961, 108, 1135.
24. Kolthoff, I. M.; Lee, T. S.; Stocesova, D.; Parry, E. P. Anal. Chem. 1950, 22, 521.
25. Zhou, X.-L.; Cowin, J. P. Submitted to J. Phys. Chem.
26. (a) Kriegman-King, M. R.; Reinhard, M. Em-iron. Sci. Technol. 1992, 26, 2198.
27. (b) Kriegman-Kins, M. R.; Reinhard, M. Environ. Sci. Technol. 1994, 28, 692.
28. HookerT P. D.; Klabunde, K. J. Environ. Sci. Technol. 1994, 28, 1243.
29. Matheson, L. J.; Tratnyek, P. G. Environ. Sci. Technol. 1994, 28, 2045.
30. Choi, W.; Hoffmann, M. R. Environ. Sci. Technol. 1995, 29, 1646.
31. Heller, H. G.; Langan, J. R. J. Chem. Soc. Perkin Trans. 1981, 2, 341. -
32. Doering, W. v. E.; Henderson, W. A., Jr. J. Am. Chem. Soc. 1958, 80, 5274.
33. Biemann, K. Mass Spectrometry-Organic Chemical Applications; McGraw Hill: New York, 1962.
34. Martin, S. T.; Herrmann, H.; Choi, W.; Hoffmann, M. R. J. Chem. Soc., Faraday Trans. 1994, 90, 3315.
35. (a) Egerton, T. A.; King, C. J. J. Oil Colour Chem. Assoc. 1979, 62, 386.
36. (b) Okamoto, K.-I.; Yamamoto, Y.; Tanaka, H.; Itaya, A. Bull. Chem. Soc. Jpn. 1985, 58, 2023.
37. Westcott, C. C. pH Measurements; Academic Press: Orlando, FL, 1978.
38. Kormann, C.; Bahnemann, D. W.; Hoffmann, M. R, Environ. Sci. Technol. 1991, 25, 494.
39. Turchi, C. S.; Ollis, D. F. J. Catal. 1990, 722, 178.
40. Rothenberger, G.; Moser, J.; Grätzel, M.; Serpone, N.; Sharma, D. K. J. Am. Chem. Soc. 1985, 707, 8054.
41. Cunningham, J.; Srijaranai, S. J. Photochem. Photobiol, A: Chem. 1988, «,329.
42. "(29) Stafford, U.; Gray, K. A.; Kamat, P. V. J. Phys. Chem. 1994, 98, 6343.
43. Robinson, E. A. J. Chem. Soc. 1961, 1663.
44. Kirmse, W. Carbene Chemistry; Organic Chemistry-A Series of Monographs, Vol. 1; Academic Press: New York, 1964.
45. Frei, H.; Fitzmaurice, D. J.; Grätzel, M. Langmuir 1990, 6, 198.