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Tetrahedron Letters

Volumn 28, Issue 20, 1987, Pages 2221-2224

Intramolecular nickel catalyzed cycloadditions of bis-dienes: 3 approaches to the taxane skeleton

(2) Wender, Paul A a Snapper, Marc L a

a STANFORD UNIVERSITY (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000332134 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)96085-4 Document Type: Article

Times cited : (95)

References (22)

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6
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7
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- Studies bearing on the syntheses of the taxanes have been reported from the laboratories of: Berkowitz, W.F.; Blechert, S.; Fetizon, M.; Gadwood, R.; Holton, R.A.; Inouye, Y.; Jenkins, P.R.; Kato, T.; Kende, A.S.; Kitagawa, I.; Martin, S.F.; Oishi, T.; Pattenden, G.; Sakan, K.; Shea, K.J.; Swindell, C.S.; Trost, B.M.; Winkler, J.D.; and Yamada, Y.

8
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- Complete references to these contributions can be found in
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- Winkler¹ Hey²

9
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10
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- (1986) J. Org. Chem. , vol.51 , pp. 793
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11
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- Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes
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- Negishi¹ Van² Yoshida³

12
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- A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes
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13
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- Negishi¹ Okukado² King³ Van⁴ Spiegel⁵

14
- 84918459328
- 3), d5.43 (m,2H); 5.17 (br d,2H); 3.64 (s,3H); 3.44(dd, 1H);3.01(m,1H); 2.47(m, 1 H); 2.42(m, 1 H); 1.90–2.10(2H); 1.34–1.65(6H); 0.92(s, 3H).

15
- 37049116392
- Conversion of 10, as outlined below, produced one product 15 in 54% yield. Stereochemistry was confirmed by comparison with published NMR data., [[Comment]]
- (1970) J. Chem. Soc. (B) , pp. 212
- Balasubrahmanyam¹ Balasubramanian²

16
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- For recent reviews of intermolecular nickel catalyzed cycloaddition reactions see
- (1985) J. Organomet. Chem. , vol.285 , pp. 343
- Tenaglia¹ Brun² Waegell³

17
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18
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- (1982) Comp. Organomet. Chem. , pp. 671
- Jolly¹

19
- 84918459326
- 3);d 5.77(br d, 1 H); 5.53(m, 1 H); 5.27(dd, 1 H); 3.76(ddd, 1 H); 3.09(dt, 1 H); 2.89(m, 1 H); 2.82(m, 1 H); 2.45(br m, 1 H); 2.11 (m, 2H); 1.98(m, 2H); 1.87(m, 1 H); 1.78(br d, 1 H); 1.45(m,1 H); 0.90(s, 9H); 0.06(s, 6H).

20
- 84918459325
- The stereochemistry of 14a and 14b was established by their individual transformation to 16a and 16b, respectively as outlined below.

21
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- Garrou¹

22
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- Alkyl Shifts between Transition Metals and Coordinated Main Group Atoms
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- Ortiz¹ Havlas² Hoffmann³

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.