Ferrocenyl Substituted Octakis(dimethylsiloxy)octasilsesquioxanes: A New Class of Supramolecular Organometallic Compounds. Synthesis, Characterization, and Electrochemistry

Organometallics

Volumn 12, Issue 11, 1993, Pages 4327-4333

  Morán, Moisés ^a   Casado, Carmen M ^a   Cuadrado, Isabel ^a   Losada, José ^b  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

^b UNIVERSIDAD POLITÉCNICA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000327523     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00035a018     Document Type: Article

References (62)

1. Metal-Containing Polymeric Systems; Sheats, J. E., Carraher, C. E., Jr., Pittman, C. U., Jr., Eds.; Plenum Press: New York, 1985.
2. Inorganic and Metal-Containing Polymeric Materials; Sheats, J. E., Carraher, C. E., Jr., Pittman, C. U., Jr., Zeldin, M, Curroell, B., Eds.; Plenum Press: New York, 1990.
3. Inorganic Polymers; Mark, J. E., Allcock, H. R., West, R., Eds.; Prentice-Hall, Inc.: Englewood Cliffs, NJ, 1992.
4. Silicon-Based Polymer Science. A Comprehensive Resource; Zeigler, J. M., Gordon Fearon, F. W., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990.
5. Advances in Organometallic and Inorganic Polymer Science, Carraher, C. E., Jr., Sheats, J. E., Pittman, C. U., Jr., Eds.; Marcel Dekker, Inc.: New York, 1982.
6. Inorganic and Organometallic Polymers; Zeldin, M., Wynne, K. J., Allcock, H. R., Eds.; ACS Symposium Series 360; American Chemical Society: Washington, DC, 1988.
7. Contemporary Polymer Chemistry, 2nd ed.; Allcock, H. R., Lampe, F. W., Eds.; Prentice Hall: Englewood Cliffs, NJ, 1990.
8. Carraher, C. E., Jr. J. Chem. Educ. 1981, 58, 921.
9. Sergeev, V. A.; Vdovina, L. I. Organomet. Chem. USSR 1989, 2, 77.
10. Marciniec, B.; Gulinski, J.; Urbaniak, W.; Kronetka, Z. W. In Comprehensive Handbook On Hydrosilylation; Marciniec, B., Ed.; Pergamon: Oxford, U.K., 1992.
11. Marciniec, B.; Gulinski, J. J. Organomet. Chem. 1993, 446, 15.
12. Lewis, L. N.; Lewis, N.; Uriarte, R. J. In Homogeneous Transition Metal Catalized Reactions; Moser, W. R., Slocum, D. W., Eds.; Advances in Chemistry Series 230; American Chemical Society: Washington, DC, 1992; p 3541.
13. Ojima, I. In The Chemistry of Organic Silicon Compounds, Part 2; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1989; p 1479.
14. Armitage, D. A. In Comprehensive Organometallic Chemistry; Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1982; Vol. 2, p 117.
15. Speier, J. L.; Adv. Organomet. Chem. 1979, 17, 407.
16. Móran, M.; Cuadrado, L.; Pascual, C.; Losada, J. Organometallics 1993, 12, 811.
17. Morán, M.; Cuadrado, I.; Pascual, C.; Casado, C. M.; Losada, J. Organometallics 1992, 11, 1210.
18. Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199–236.
19. Day, V. W.; Klemperer, W. G.; Mainz, V. V.; Millar, D. M. J. Am. Chem. Soc. 1985, 107, 8262.
20. Agaskar, P. A.; Day, V. W.; Klemperer, W. G. J. Am. Chem. Soc. 1987, 109, 5554.
21. Kreuzer, F. H.; Maurer, R.; Spes, P. Makromol. Chem., Macromol. Symp. 1991, 50, 215.
22. Herren, D.; Bürgy, H.; Calzaferri, G. Helv. Chim. Acta 1991, 74, 24.
23. When this work was in progress an example of an organometallic monosubstituted octanuclear silsesquioxane was reported: Calzaferri, G.; Imhof, R. J. Chem. Soc, Dalton Trans. 1992, 3391.
24. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
25. Gibson, C. P.; Bern, D. S.; Falloon, S. B.; Hitchens, T. K.; Cortopassi, J. E. Organometallics 1992, 11, 1742.
26. Gibson, C. P.; Bern, D. S.; Falloon, S. B.; Cortopassi, J. E. In Inorganic and Metal-Containing Polymeric Materials; Sheats, J. E., Carraher, C. E., Jr., Pittman, C. U., Jr., Zeldin, M., Currell, B., Eds.; Plenum Press: New York, 1990; p 127.
27. See for example: Sakamoto, K.; Nishihara, H.; Aramaki, K. J. Chem. Soc, Dalton Trans. 1992, 1877.
28. Eaves, J. G.; Munro, H. S.; Parker, D. Inorg. Chem. 1987, 26, 644.
29. Jönsson, G.; Gorton, L.; Pettersson, L. Electroanalysis 1989, 49.
30. Inagaki, T.; Lee, H. S.; Skotheim, T. A.; Okamoto, Y. J. Chem. Soc, Chem. Commun. 1989, 1181.
31. Hale, P. D.; Lan, H. L.; Boguslavsky, L. L.; Karan, H. I.; Okamoto, Y.; Skotheim, T. A. Anal. Chim. Acta 1991, 251, 121.
32. Hale, P. D.; Boguslavsky, L. I.; Inagaki, T.; Karan, H. L.; Lee, H. S.; Skotheim, T. A.; Okamoto, Y. Anal. Chem. 1991, 63, 677.
33. Tabakovic, R.; Tabakovic, L.; Davidovic, A.; Zupan, M. J. Electroanal. Chem. 1992, 332, 297.
34. Hale, P. D.; Inagaki, T.; Karan, H. I.; Okamoto, Y.; Skotheim, T. A. J. Chem. Soc 1989, 111, 3482.
35. Mizutani, F.; Yabuki, S.; Okuda, A.; Katsura, T. Bull. Chem. Soc. Jpn. 1991, 64, 2849.
36. Stein, J.; Lewis, L. N.; Smith, K. A.; Lettko, K. X. J. Inorg. Organomet. Polym. 1991, 1, 325.
37. Liu, H. Q.; Harrod, J. F. Can. J. Chem. 1990, 68, 1100.
38. Puyenbroek, R.; Jekel, A. P.; van de Grampel, J. C. J. Inorg. Organomet. Polym. 1991, 1, 105.
39. Lestel, L.; Boileau, S.; Cheradame, H. Polym. Prepr. (Am. Chem. Soc, Div. Polym. Chem.) 1989, 30, 133.
40. Akademie der Wissenschaften der DDR, Inv. EP-A 0348705, 1990; Hoebbel, D.; Pitsch, I.; Hiller, W.; Scheim, S. Chem. Abstr. 1990, 113, 125354b.
41. Wacker-Chemie GmbH, Inv. EP-A 0367222, 1990; Weidner, R.; Zeller, N.; Deubzer, B.; Frey, V. Chem. Abstr. 1990, 113, 116465m.
42. Chloroplatinic acid has been recently reported to be unsuitable for some hydrosilylation reactions, as questionable results were obtained. See for example: Allcock, H. R.; Nelson, C. J.; Coggio, W. D. Organometallics 1991, 10, 3819.
43. The oxygen effect in hydrosilylations has been discussed in detail by L. N. Lewis. See: Lewis, L. N. J. Am. Chem. Soc. 1990, 112, 5998.
44. Lewis, L. N.; Lewis, N. Chem. Mater. 1989, 1, 106.
45. Lewis, L. N.; Uriarte, R. J. Organometallics 1990, 9, 621.
46. In some cases formation ofα; and β isomers from SiH addition to vinyl derivatives has been observed: Lewis, L. N.; Uriarte, R. J.; Lewis, N. J. Catal. 1991, 127, 67.
47. Aoyagi, T.; Akimoto, T.; Nagase, Y. Makromol. Chem. 1992, 193, 2821.
48. Marignan, G.; Teyssié, D.; Boileau, S.; Malthête, J.; Noël, C. Polymer 1988, 29, 1318.
49. The Analytical Chemutry of Silicones; Smith, A. L., Ed.; John Whiley & Sons, Inc.: New York, 1991.
50. Gonsalves, K. E.; Rausch, M. D. J. Polym. Sci., Polym. Chem. Ed. 1986, 24, 1599.
51. Gozdz, A. S.; Reich, H. J.; Bowe, M. D. In Silicon-Baaed Polymer Science. A Comprehensive Resource; Zeigler, J. M., Gordon Fearon, F. W., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990.
52. Abrufia, H. D. Coord. Chem. Rev. 1988, 86, 135.
53. Smith, D. F.; William, K.; Kuo, K.; Murray, R. M. J. Electroanal. Chem. Interfacial Electrochem. 1979, 95, 217.
54. Peerce, P. J.; Bard, A. J. J. Electroanal. Chem. Interfacial Electrochem. 1980, 114, 89.
55. Laviron, E. J. Electroanal. Chem. Interfacial Electrochem. 1979, 105, 35.
56. Laviron, E. J. Electroanal. Chem. Interfacial Electrochem. 1979, 105, 25.
57. Laviron, E. J. Electroanal. Chem. Interfacial Electrochem. 1979, 100, 263.
58. Laviron, E. J. Electroanal. Chem. Interfacial Electrochem. 1974, 52, 395.
59. Murray, R. W. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1984; Vol. 13, p 191.
60. De Long, H. C.; Butty, D. A. Langmuir 1990, 6, 1319.
61. Perrin, D. D.; Armarego, W. L. F.; Perrin, D. R. Purification of Laboratory Chemicals, 2nd ed.; Pergamon: New York, 1988.
62. Ogaaa, M.; Mallin, D. T.; Macomber, D. W.; Rausch, M. D.; Rogers, R. D.; Rollins, A. N. J. Organomet. Chem. 1991, 405, 41.