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There are, however, a couple of examples where this appears not to be the case, especially at temperatures below 77 K. In refs 18, 23, 44, and 45, alternative deactivation models are discussed for TIN P, some benzotriazole-methyl methacrylate copolymers, and monoaryltriazines.
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It is known that compounds embedded in polymers sometimes show more complicated emission kinetics, especially at low temperatures, than in liquid solution. This may be due to an inhomogeneous distribution of sites in a solid matrix (see refs 55 and 56). A similar effect might be responsible for the difference in fluorescence kinetics between solid TIN P and MA-TIN 1.
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