Synthesis and structure of [tris(trimethylsilyl)silyl]-substituted gallanes and gallates

Chemische Berichte

Volumn 129, Issue 5, 1996, Pages 561-569

  Linti, Gerald ^a,b   Frey, Ronald ^a   Köstler, Wolfgang ^a   Urban, Horst ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b UNIVERSITY OF MUNICH   (Germany)

Author keywords

Gallium alkoxides; Gallium compounds; Hydroxygallium compounds; Silylgallanes

Indexed keywords

EID: 0000323557     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290514     Document Type: Article

References (50)

1. G. Linti, W. Köstler, Angew. Chem. 1996, 108, 593;
2. Angew. Chem. Int. Ed. Engl. 1996, 35, 550.
3. L. Rösch, H. Neumann, Angew. Chem. 1980, 92, 62;
4. Angew. Chem. Int. Ed. Engl. 1980, 19, 55.
5. A. M. Arif, A. H. Cowley, T. M. Elkins, R. A. Jones, J. Chem. Soc., Chem. Commun. 1986, 1776.
6. R. Frey, G. Linti, K. Polborn, Chem. Ber. 1994, 127, 101.
7. G. Linti, J. Organomet. Chem., submitted.
8. [6a] H. Gilman, C. L. Smith, J. Organomet. Chem. 1968, 74, 91.
9. [6b] G. Gutekunst, A. G. Brook, J. Organomet. Chem. 1982, 225, 1.
10. [6c] A. Heine, R. Herbst-Irmer, G. M. Sheldrick, D. Stalke, Inorg. Chem. 1993, 32, 2694.
11. G. Linti, R. Frey, K. Polborn, Chem. Ber. 1994, 127, 1387.
12. [8a] M. B. Power, W. M. Cleaver, A. W. Ablett, A. R. Barron, J. W. Ziller, Polyhedron 1992, 11, 477.
13. [8b] D. A. Atwood, A. H. Cowley, P. R. Harris, R. A. Jones, S. U. Koschmieder, C. M. Nunn, Organometallics 1993, 12, 24.
14. [8c] M. B. Power, J. W. Ziller, A. R. Barron, Organometallics 1992, 11, 2783.
15. J. L. Hoard, G. S. Smith, J. Am. Chem. Soc. 1959, 81, 3907.
16. B. Neumüller, F. Gahlmann, Angew. Chem. 1993, 105, 1770;
17. Angew. Chem. Int. Ed. Engl. 1993, 32, 1701.
18. J. Storre, T. Belgardt, D. Stalke, H. W. Roesky, Angew. Chem. 1994, 106, 1365;
19. Angew. Chem. Int. Ed. Engl. 1994, 33, 1244.
20. C. C. Landry, C. J. Harlan, S. G. Bott, A. R. Barron, Angew. Chem. 1995, 107, 1315;
21. Angew. Chem. Int. Ed. Engl. 1995, 34, 1201.
22. A. H. Cowley, F. P. Gabbai, D. A. Atwood, J. Am. Chem. Soc. 1994, 116, 1559.
23. M. H. Chisholm, V. F. DiStasi, W. E. Steib, Polyhedron 1991, 9, 253.
24. [15a] H. Sinn, W. Kaminsky, Adv. Organomet. Chem. 1980, 18, 99.
25. [15b] K. Ziegler, GB-B 775384, 1957 [Chem. Abstr. 1958, 52, 12893e].
26. C. J. Harlan, M. R. Mason, A. R. Barron, Organometallics 1994, 13, 2957.
27. H. C. Marsmann, W. Raml, E. Hengge, Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1980, 35, 1541.
28. A. Heine, D. Staike, Angew. Chem. 1993, 105, 90;
29. Angew. Chem. Int. Ed. Engl. 1993, 52, 121.
30. [19a] V. Shomaker, D. P. Stevenson, J. Am. Chem. Soc. 1941, 63, 37.
31. 1.4[Pm].
32. Used covalent radii for gallium are 126 pm and 117 pm for silicon: J. E. Huheey, Anorganische Chemie, W. de Gruyter, Berlin, New York, 1988.
33. M. A. Petrie, P. P. Power, H. V. R. Dias, K. Ruhlandt-Senge, K. M. Waggoner, R. J. Wehmschulte, Organometallics 1993, 12, 1086.
34. A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon Press, Oxford, 1995.
35. A. H. Cowley, S. K. Mehratra, J. L. Atwood, W. Hunter, Organometallics 1985, 4, 1115.
36. D. A. Atwood, A. H. Cowley, R. A. Jones, M. A. Mardones, J. L. Atwood, S. G. Bott, J. Coord. Chem. 1992, 26, 285.
37. A. H. Cowley, A. Decken, C. A. Olazábal, N. C. Norman, Inorg. Chem. 1994, 33, 3435.
38. A. R. Barron, K. D. Dobbs, M. M. Francl, J. Am. Chem. Soc. 1991, 113, 39.
39. D. A. Atwood, A. H. Cowley, R. A. Jones, M. Mardones, J. L. Atwood, S. G. Bott, J. Coord. Chem. 1992, 25, 233.
40. R. D. Schluter, H. S. Isom, A. H. Cowley, D. J. Atwood, R. A. Jones, F. Olbrich, S. Corbelin, R. J. Lagow, Organometallics 1994, 13, 4058.
41. W. C. Hamilton, J. C. Ibers, Hydrogen Bonding in Solids, W. A. Benjamin, New York, 1968.
42. See for example: H. Chen, R. A. Bartlett, M. M. Olmstead, P. P. Power, S. C. Shoner, J. Am. Chem. Soc. 1990, 112, 1048.
43. N. W. Alcock, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1971, 27, 1682.
44. Further details of the crystal structure investigations are available on request from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen, on quoting the depository numbers CSD-404471 (15), CSD-404472 (13), CSD-404473 (7), CSD-404474 (9), CSD-404475 (12), and CSD-404480 (10).
45. M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Bmkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez, J. A. Pople, Gaussian 94, Revision B.2. Gaussian, Inc., Pittsburgh PA, 1995. P4]
46. T. H. Dunning, Jr., P. J. Hay in Modern Theoretical Chemistry (Ed.: H. F. Schäfer, III), Plenum, New York, 1976, p. 1-28;
47. P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 270;
48. W. R. Wadt, P. J. Hay, ibid. 1985, 82, 284;
49. P. J. Hay, W. R. Wadt, ibid. 1985, 82, 299.
50. Brauer, Handbuch der präparativen Anorganischen Chemie, F. Enke, Verlag, Stuttgart, 1975.