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Volumn 2, Issue 8, 1996, Pages 1001-1006

A straightforward, highly stereoselective synthesis of protected isostatine derivatives

Author keywords

Aminopolyols; Asymmetric aminations; Asymmetric epoxidation; Asymmetric hydroxylation; Didemnins

Indexed keywords

AMINOPOLYOLS; ASYMMETRIC AMINATIONS; ASYMMETRIC EPOXIDATION; CATALYTIC ASYMMETRIC EPOXIDATION; DIDEMNINS; ENANTIOSELECTIVE PREPARATION; NOVEL STRATEGIES; STEREOSELECTIVE SYNTHESIS;

EID: 0000318415     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960020816     Document Type: Article
Times cited : (26)

References (48)
  • 4
    • 84890839691 scopus 로고
    • U. S. Patent 4493796
    • K. L. Rinehart, U. S. Patent 4493796, 1985;
    • (1985)
    • Rinehart, K.L.1
  • 5
    • 4243649195 scopus 로고
    • Chem. Abstr. 1985, 103, 76241 v.
    • (1985) Chem. Abstr. , vol.103
  • 11
    • 84890825279 scopus 로고    scopus 로고
    • B. Castro, P. Jouin, A. Cavé, M. Dufour, B. Banaigs, C. Francisco in ref. [4a]. pp. 656-657
    • b) B. Castro, P. Jouin, A. Cavé, M. Dufour, B. Banaigs, C. Francisco in ref. [4a]. pp. 656-657.
  • 23
    • 84890849532 scopus 로고    scopus 로고
    • note
    • 2 [7g,10].
  • 44
    • 84890851796 scopus 로고    scopus 로고
    • note
    • 5, was detected spectroscopically (see Experimental section).
  • 46
    • 84890809812 scopus 로고    scopus 로고
    • note
    • 2).
  • 47
    • 84890851384 scopus 로고    scopus 로고
    • note
    • The diastereomeric excess of 11 was established by comparison with the mixture obtained by treatment of the allyl alcohol 10 (1.87 mmol) with m-chloroperbenzoic acid (3.75 mmol) in the presence of sodium carbonate (5.62 mmol) in dichloromethane solution (15 mL) at room temperature for 3.5 h, which gave a 4:6 mixture of 11 and the (2R,3R,4S) diastereomer (78% yield after chromatographic purification).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.