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84890851796
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5, was detected spectroscopically (see Experimental section).
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45
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84890809812
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-
note
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2).
-
-
-
-
47
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-
84890851384
-
-
note
-
The diastereomeric excess of 11 was established by comparison with the mixture obtained by treatment of the allyl alcohol 10 (1.87 mmol) with m-chloroperbenzoic acid (3.75 mmol) in the presence of sodium carbonate (5.62 mmol) in dichloromethane solution (15 mL) at room temperature for 3.5 h, which gave a 4:6 mixture of 11 and the (2R,3R,4S) diastereomer (78% yield after chromatographic purification).
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