Bis(ethylenedithio)tetraselenafulvalene: Short-cut synthesis, X-ray crystal structure and π-electron density distribution

New Journal of Chemistry

Volumn 22, Issue 6, 1998, Pages 585-589

  Courcet, Thierry ^a   Malfant, Isabelle ^a   Pokhodnia, Konstantin ^a,b   Cassoux, Patrick ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b INSTITUTE OF SEMICONDUCTOR PHYSICS   (Ukraine)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000317649     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/a709176a     Document Type: Article

References (24)

1. J. M. Williams, H. H. Wang, T. J. Emge, U. Geiser, M. A. Beno, P. C. W. Leung, K. D. Carlson, R. J. Thorn, A. J. Schultz and M.-H. Whangbo, Prog. Inorg. Chem., 1987, 35, 51.
2. H. Kobayashi, H. Tomita, T. Naito, A. Kobayashi, F. Sakai, T. Wantanabe and P. Cassoux, J. Am. Chem. Soc., 1996, 118, 368.
3. R. Kato, H. Kobayashi and A. Kobayashi, Synth. Metals, 1991, 42, 2093.
4. T. Naito, A. Miyamoto, H. Kobayashi, R. Kato and A. Kobayashi, Chem. Lett., 1991, 1945;
5. L. K. Montgomery, T. Burgin, J. C. Huffman, K. D. Carlson, J. D. Dudek, G. A. Yaconi, L. A. Megna, P. R. Mobley, W. W. Kwok, J. M. Williams, J. E. Shirber, D. L. Overmyer, J. Ren, C. Rovira and M.-H. Whangbo, Synth. Metals, 1993, 56, 2090.
6. H. Kobayashi, T. Udagawa, H. Tomita, K. Bun, T. Naito and A. Kobayashi, Chem. Lett., 1993, 1559;
7. L. K. Montgomery, T. Burgin, J. C. Huffman, J. Ren and M.-H. Whangbo, Physica C, 1994, 219, 490;
8. H. Kobayashi, H. Tomita, T. Naito, H. Tanaka, A. Kobayashi and T. Saito, J. Chem. Soc., Chem. Commun., 1995, 1225;
9. H. Kobayuashi, T. Naito, A. Sato, K. Kawano, A. Kobayashi, H. Tanaka, T. Saito, M. Tokumoto, L. Brossard and P. Cassoux, Mol. Cryst. Liq. Cryst., 1996, 284, 61.
10. F. Goze, V. N. Laukhin, L. Brossard, A. Audouard, J. P. Ulmet, S. Askenazy, T. Naito, H. Kobayashi, A. Kobayashi, M. Tokumoto and P. Cassoux, Europhys. Lett., 1994, 28, 6, 427.
11. A. Kobayashi, T. Udagawa, H. Tomita, T. Naito and H. Kobayashi, Chem. Lett., 1993, 2179.
12. R. R. Schumaker, V. Y. Lee and E. M. Engler, IBM Research Report, 1983.
13. W. E. Parham, J. Heberling and H. Wynberg, J. Am. Chem. Soc., 1955, 77, 1169.
14. K. Lerstrup, M. Lee, F. M. Wiygul, T. J. Kistenmacher and D. O. Cowan, J. Chem. Soc., Chem. Commun., 1983, 294;
15. L.-Y. Chiang, P. Shu, D. Holt and D. Cowan, J. Org. Chem., 1983, 48, 4713.
16. 1/c, a = 6.662 Å, b = 14.227 Å, c = 16.216 Å, β = 92.97°. The structure described in this paper was determined at low temperature (160 K) and the refinements were conducted with a Draconian criterion for observed reflections [I > 0 σ(I)] made possible by the high quality of the crystal.
17. H. Kobayashi, A. Kobayashi, Y. Sasaki, G. Saito and H. Inokuchi, Bull. Chem. Soc. Jpn., 1986, 59, 301.
18. A. Kini, B. D. Gates, M. A. Beno and J. M. Williams, J. Chem. Soc., Chem. Commun., 1989, 169.
19. PM3 is a reparameterization of the AMI method; see for example: M. J. S. Dewar, E. G. Zoebisch, E. F. Healy and J. S. Steward, J. Am. Chem. Soc., 1985, 107, 3902.
20. Atomic coordinates taken from this work for BETS, from ref. 12 for ET and ref. 13 for BEST.
21. R. Kato, S. Aonuma, Y. Okano, H. Sawa, A. Kobayashi and H. Kobayashi, Synth. Metals, 1993, 56, 2084.
22. H. H. Wang, L. K. Montgomery, U. Geiser, L. C. Porter, K. D. Carlson, J. R. Ferraro, J. M. Williams, C. S. Cariss, R. L. Rubinstein and J. R. Whitworth, Chem. Mater., 1989, 1, 140.
23. R. Kato, H. Kobayashi, A. Kobayashi and Y. Sasaki, Chem. Lett., 1984, 1693.
24. For ET and BEST, the C ratio is calculated from the corresponding atomic coordinates taken from ref. 12 and 13, respectively.