Stepwise versus Concerted Electron Transfer-Bond Fragmentation in the Reduction of Phenyl Triphenylmethyl Sulfides

Journal of Physical Chemistry A

Volumn 103, Issue 21, 1999, Pages 4141-4143

  Jakobsen, Steen ^a   Jensen, Henrik ^a   Pedersen, Steen U ^a   Daasbjerg, Kim ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000311658     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp990087e     Document Type: Article

References (31)

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21. o = 0.480 V vs SCE. The setup and procedures were as previously described:
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27. 7 ET processes.
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29. 3), and 0.42 V vs SCE (X = CN).
30. -1, see ref 3b. These values of BDE and BDFE were also used for the three other sulfides since the substituent effect is expected to be relatively small.
31. 1b,7b