Attempted generation of the thionylphosphazene cation [NSO(NPCl 2)2]+: Novel reactivity and the discovery of an ambient temperature ring-opening polymerization route to poly(thionylphosphazenes)

Journal of the American Chemical Society

Volumn 120, Issue 13, 1998, Pages 3249-3250

  Gates, Derek P ^a   Edwards, Mark ^a   Liable Sands, Louise M ^a   Rheingold, Arnold L ^b   Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000306960     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9740475     Document Type: Letter

References (46)

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31. ν = 18.2.
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33. 4] has been invoked in aromatic sulfonylation reactions (Jensen, F. R.; Goldman, G. In FriedelCrafts and Related Reactions, Vol. 3;
34. 2Cl, rather than an ion pair.
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41. +, 1%).
42. ν = 6.8.
43. w = 34 000; PDI = 1.9.
44. 2] in the liquid state over several days at 25 °C has previously been reported:
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