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Volumn 574, Issue 1, 1999, Pages 142-147

Synthesis and structure of 1,3-dienolate (CH2C(O)CH=CH2) complex of dipalladium(I) moiety: Contribution of π-olefin co-ordination of enolate to transition metal

Author keywords

Dinuclear; Enolate; Palladium

Indexed keywords


EID: 0000305833     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00934-6     Document Type: Article
Times cited : (14)

References (29)
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    • All three co-ordination modes were also found in the β-dicarbonyl anion (RC(O)CHC(O)R′)-palladium complexes in: H. Yaozeng, A. Yamamoto, B.-K. Teo (Eds.) Science Press, Beijing
    • All three co-ordination modes were also found in the β-dicarbonyl anion (RC(O)CHC(O)R′)-palladium complexes. S. Kawaguchi, in: H. Yaozeng, A. Yamamoto, B.-K. Teo (Eds.), New Frontiers in Organometallic and Inorganic Chemistry, Science Press, Beijing, 1984, p. 101.
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    • This value of dihedral angle reflects the degree of displacement of carbonyl carbon (C3/C2′) from the plane formed by the other dienolate carbons, while the mean dihedral angle between C1-C2-C4/C1-C3′-C4 and Pd1-Pd2-Cl1 core is 95°, near to 90°
    • This value of dihedral angle reflects the degree of displacement of carbonyl carbon (C3/C2′) from the plane formed by the other dienolate carbons, while the mean dihedral angle between C1-C2-C4/C1-C3′-C4 and Pd1-Pd2-Cl1 core is 95°, near to 90°.


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