Analyzing Product Inhibition and pH Gradients in Immobilized Enyme Films As Illustrated Experimentally by Immunologically Bound Glucose Oxidase Electrode Coatings

Journal of Physical Chemistry B

Volumn 103, Issue 40, 1999, Pages 8532-8537

  Bourdillon, Christian ^b   Demaille, Christophe ^a   Moiroux, Jacques ^a   Savéant, Jean Michel ^a  

^a UNIVERSITÉ PARIS DIDEROT   (France)

^b UNIVERSITÉ DE TECHNOLOGIE DE COMPIÈGNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000305609     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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33. 8d,g from experiments in which the electrode coating was made of one active monolayer deposited on top of 10 inactivated monolayers. Under these conditions, the catalytic currents are low enough for product inhibition to be negligible.
34. (a) For a film made of N successive monolayers, one obtains (see Supporting Information) a series of equations which are the same as the finite difference equations that appear in the approximate resolution of continuous systems obeying Fick's law. Thus, for continuous systems, one may divide the film thickness into a finite number of intervals and apply the same procedures as used here to the resulting finite difference equations.
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