Recognition of Dyes by K2SO4 Crystals: Choosing Organic Guests for Simple Salts

Journal of the American Chemical Society

Volumn 116, Issue 12, 1994, Pages 5519-5520

  Kelley, Michael P ^a   Janssens, Bart ^a   Kahr, Bart ^a   Vetter, William M ^b  

^a PURDUE UNIVERSITY   (United States)

^b STONY BROOK UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000303551     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00091a086     Document Type: Article

References (15)

1. Mann, S.; Archibald, D. D.; Didymus, J. M.; Douglas, T.; Heywood, B. R.; Meldrum, F. C.; Reeves, N. J. Science 1993, 261, 1286. Addadi, L.; Weiner, S. Angew. Chem., Int. Ed. Engl. 1992, 31, 153.
2. Izumi, Y.; Urabe, K.; Makoto, O. Zeolite, Clay, and Heteropoly Acid in Organic Reactions; VCH: New York, 1992. Klein, L. C. Sol-Gel Optics: Processing and Applications: Kluwer: Dordrecht, 1993. Ramamurthy, V., Ed. Photochemistry in Organized and Constrained Media; VCH: New York, 1991. See also: Kirkor, E. S.; David, D. E.; Michl, J. J. Am. Chem. Soc. 1990, 112, 139. Böttcher, H.; Hertz, O.; Fox, M. A. Chem. Phys. Leu. 1989, 160, 121.
3. de Sénarmont, H. Ann. Phys. (Leipzig) 1854, 167, 491.
4. Buckley, H. E. Z. Kristallogr. 1934, 88, 248. Buckley, H. E. Crystal Growth; John Wiley: New York, 1951; pp 377-378.
5. Part XII: France, W. G.; Wolfe, K. M. J. Am. Chem. Soc. 1941, 63, 1505.
6. For some structural inferences, see: Neuhaus, A. Angew. Chem. 1941, 54, 527.Slavnova, E. N. Growth of Crystals; Consultants Bureau: New York, 1958; pp 117-125. Hartmann, H. Zur Physik und Chemie der Kristall-phosphore; Akademie-Verlag: Berlin, 1960; p 136.
7. 4 and argue against dye aggregation. Dudley, M.; Vetter, W.; Kahr, B. In National Synchrotron Light Source Report: Hurlburt, S. L., Lazarz, M. L., Eds.; Brookhaven National Laboratory: Upton, New York, 1993; in press. Thegrowth of these crystals was described as an experiment for students. Kahr, B.; Chow, J. K.; Peterson, M. J. Chem. Educ, in press.
8. In order to be consistent with Buckley, Miller indices refer to ratios determined by classical goniometry: a = 5.772 Å, b = 10.072 Å, c = 7.483 Å for Pmcn, No. 62. See: von Groth, P. Chemische Krystallographie, v. 2; WilhelmEngelmann: Leipzig, 1908; p 337. Wyckoff, R.G. Crystal Structures, v. 3; Wiley Interscience: New York, 1965; p 95.
9. Dewar, M. J. S.; Zoebisch, E. G.; Healy, E. F.; Stewart, J. J. P. J. Am. Chem. Soc. 1985, 107, 3902. Stewart, J. J. P. Quantum Chemistry Program Exchange, Bloomington, Indiana, No. 455.
10. Hartshorne, N. H.; Stuart, A. Crystals and the Polarizing Microscope, 4th ed. Edward Arnold: London, 1970. Michl, J.; Thulstrup, E. W. Spectroscopy with Polarized Light, VCH: New York, 1986.
11. Ridley, J.; Zerner, M. C. Theor. Chim. Acta 1973, 32, 111; 1976, 42, 223.
12. Lueck, H. B.; McHale, J. L.; Edwards, W. D. J. Am. Chem. Soc. 1992, 114, 2342.
13. Davey, R. J.; Black, S. N.; Bromley, L. A.; Cottier, D.; Dobbs, B.; Rout, J. E. Nature 1991, 353, 549. Kelley, M. P.; Chow, J. K.; Kahr, B. Mol. Cryst. Liq. CrySt. 1994, 242, 201.
14. 3-anions. We could not reconcile Whetstone's dye structures with the results of our semiempirical MO calculations. His geometries were taken from unpublished reports of the German dye industry, collected by British teams after World War II, in which triarylmethane dyes were mistakenly described as flat, not propeller-shaped. See: BIOS (British Intelligence Objectives Subcommittee) microfilm, R20, P. B. 73,564, FDX 226. For a listing, refer to: Bibliography of Scientific and Industrial Reports, Vols. 1-11 (19461949).
15. Pouxviel, J. C.; Dunn, B.; Zink, J. I. J. Phys. Chem. 1989, 93, 2134.