Free-radical cyclization of enantiomerically enriched 2-p-tolylthio derivatives of 2-allylcyclohexanones with Mn(III): Asymmetric synthesis of bridged bicyclic ketones and thiochroman-3-ones

Tetrahedron Asymmetry

Volumn 10, Issue 22, 1999, Pages 4427-4436

  Garcia Ruano J L ^a   Rumbero, A ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXANONE DERIVATIVE; KETONE; MANGANESE; THIOCHROMAN DERIVATIVE; THIOL DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CYCLIZATION; ENANTIOMER; MOLECULAR INTERACTION; PRIORITY JOURNAL; REACTION ANALYSIS; SYNTHESIS;

EID: 0000299647     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(99)00467-X     Document Type: Article

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52. 2) regardless of the conformational behavior of the substrates. Nevertheless, the fact that reaction time required for the complete evolution of compound 9 was larger (36 h) than that for 4 (8 h) suggests to us that this is not the case and other factors must be involved.