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Volumn 101, Issue 23, 1997, Pages 4254-4262

Cation-ether complexes in the gas phase: Bond dissociation energies of K+(dimethyl ether)x x = 1-4; K+(1,2-dimethoxyethane)x, x = 1 and 2; and K+(12-crown-4)

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EID: 0000294055     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp964015o     Document Type: Article
Times cited : (95)

References (56)
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    • note
    • The necessary conditions for the kinetic method to be useful are (i) competitive reactions must have identical frequency factors, so that their rates are controlled by their activation energies and, (ii) reverse activation energies, which are expected to be small, must be equivalent.
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