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Volumn 35, Issue 17, 1996, Pages 5032-5039

Solvent Cage Effects in Organocobalt Corrinoid Chemistry: Thermal Homolysis of α- And β-(Cyanomethyl)cobinamides 1

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Indexed keywords


EID: 0000285240     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9603666     Document Type: Article
Times cited : (15)

References (115)
  • 1
    • 2542559916 scopus 로고    scopus 로고
    • note
    • 2-4-HTEMPO, N-(cyanomethoxy)-4-hydroxy-2,2,6,6-tetramethylpiperidine. Note that all organocobalt corrinoids referred to are assumed to have the organic ligand in the β axial position unless explicitly stated otherwise.
  • 23
    • 85088077577 scopus 로고    scopus 로고
    • 17,23
    • 17,23
  • 26
    • 85088077967 scopus 로고    scopus 로고
    • 26
    • 26
  • 45
    • 85088077755 scopus 로고    scopus 로고
    • 27a,b,f,32,53a-d
    • 27a,b,f,32,53a-d
  • 93
    • 2542607069 scopus 로고    scopus 로고
    • Note, however, the uncertainties regarding possible other products in the study described in ref 16, as discussed in the Introduction and in footnote 12 of ref 18.
    • Note, however, the uncertainties regarding possible other products in the study described in ref 16, as discussed in the Introduction and in footnote 12 of ref 18.
  • 95
    • 85088076639 scopus 로고    scopus 로고
    • 16 (however, see ref 63)
    • 16 (however, see ref 63).
  • 96
    • 2542559914 scopus 로고    scopus 로고
    • note
    • 2· motion.
  • 104
    • 85088079345 scopus 로고    scopus 로고
    • 71
    • 71
  • 106
    • 85088077324 scopus 로고    scopus 로고
    • note
    • + ground state must still leave significant steric interactions between the Np ligand and the "downwardly" projecting side chains leading to a decrease in ground state entropy. However, if such flexing is reduced as steric pressure is reduced approaching the ground state, the increased steric interaction in the transition state might lead to a very low entropy of activation.
  • 107
    • 85087189412 scopus 로고
    • Dolphin, D., Ed.; Wiley-Intersciernce: New York
    • 12; Dolphin, D., Ed.; Wiley-Intersciernce: New York, 1982; Vol. 1.
    • (1982) 12 , vol.1
    • Glusker, J.P.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.