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We recently found that in N-alkyl-N-9-triptycylacetamides where the alkyl is methyl or ethyl, the amide nitrogen atom is significantly pyramidalized both in crystal and in solution: G. Yamamoto, H. Murakami, N. Tsubai, and Y. Mazaki, Chem. Lett., 1997, 605; G. Yamamoto, N. Tsubai, H. Murakami, and Y. Mazaki, Chem. Lett., 1997, 1295.
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We recently found that in N-alkyl-N-9-triptycylacetamides where the alkyl is methyl or ethyl, the amide nitrogen atom is significantly pyramidalized both in crystal and in solution: G. Yamamoto, H. Murakami, N. Tsubai, and Y. Mazaki, Chem. Lett., 1997, 605; G. Yamamoto, N. Tsubai, H. Murakami, and Y. Mazaki, Chem. Lett., 1997, 1295.
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Sandström, J.1
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S. Forsén and R. A. Hofmann, J. Chem. Phys., 39, 2892 (1963); J. Sandström. "Dynamic NMR Spectroscopy," Academic Press. London (1982), Chap. 4; G. Yamamoto, Bull. Chem. Soc. Jpn., 65, 1967 (1992).
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Yamamoto, G.1
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