Pyridine functionalized alkyls of transition metals. Synthesis of bis[C,N-2-pyridylbis(trimethylsilyl)methyl]nickel

Polyhedron

Volumn 12, Issue 13, 1993, Pages 1613-1620

  Izod, Keith J ^a   Thornton, Peter ^a  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000271138     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(00)87071-0     Document Type: Article

References (24)

1. Syntheses and structures of highly hindered N-functionalised alkyl?group 2 metal complexes [M{NC5H4C(SiMe3)2-2}2](M = Mg, Zn, Cd, or Hg)
2. Alkylaluminum Cations: Synthesis and Structure of
3. The first monomeric crystalline tin(II) alkyls; X-ray structures of the ?-N-functionalised alkyls Sn(R)X [R?= C?(SiMe3)2C5H4N?2 and X?= R?, Cl?, or N?(SiMe3)2]
4. Synthesis of pyridine functionalised, sterically hindered lithium and copper (I) alkyls; crystal structures of [{2-(Me3Si)2C(M)C5H4N}2](M = Li or Cu), dimeric compounds free of multicentre bonding
5. NMR Studies of Picolyl-type Carbanions. IV. Anions Produced by Reactions of 2-Substituted Pyridines with Butyllithium
6. Syntheses and crystal structures of complexes [M2R2][M = Cu, Ag, or Au; R = 2-C(SiMe3)2C5H4N] and [Cu4R?4][R?= 2-CH(SiMe3)C5H4N]; electrochemical generation of [Cu2R2]2+
7. Alkylation of (As, Sb, Bi)Cl3: formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CH?C)(SiMe3)(C5H4N-2)] and 2-CH(SiMe3)2C5H4N-5-R [R = C(SiMe3)2C5H4N-2]
8. Lithiation of 2-Me3SiCHRC5H4N(R = H or SiMe3): influence of solvent on the nature of the product (from X-ray structure determinations) and asymmetric induction. A note on the lithiation of some analogous 3- and 4-methylpyridines