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Volumn 36, Issue 15, 1997, Pages 3307-3317

Electrochemistry of Oxygenation Catalysts. 3.1 Thermodynamic Characterization of Electron Transfer and Solvent Exchange Reactions of Co(salen)/[Co(salen)]+ in DMF, Pyridine, and Their Mixtures

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EID: 0000270624     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9703336     Document Type: Article
Times cited : (46)

References (82)
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    • For part 2, see ref 35
    • For part 2, see ref 35.
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    • Agarvala, B. V., Munshi, K. N., Eds.; World Scientific: Singapore
    • Basolo, F. In Facets of Coordination Chemistry; Agarvala, B. V., Munshi, K. N., Eds.; World Scientific: Singapore, 1993; pp 24-45.
    • (1993) Facets of Coordination Chemistry , pp. 24-45
    • Basolo, F.1
  • 31
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    • Eichhorn, E.; Rieker, A.; Speiser, B. Angew. Chem. 1992, 104, 1246-1248; Angew. Chem., Int. Ed. Engl. 1992, 31, 1215-1217.
    • (1992) Angew. Chem., Int. Ed. Engl. , vol.31 , pp. 1215-1217
  • 32
    • 1542617872 scopus 로고    scopus 로고
    • note
    • 0 in Scheme 1 denote the solvent molecules attached to the Co central atom in both partners of the redox couple. The superscripts in the K symbolize the oxidation state of the central Co atom; the first part of the subscripts defines the fixed solvent molecule, while the second and third show the two exchanging ligands, arranged in the order of increasing basicity. The exchanging solvent molecules have been omitted from the equilibrium arrows in the scheme.
  • 33
    • 85086290296 scopus 로고    scopus 로고
    • note
    • 2) will be used.
  • 34
    • 0004287057 scopus 로고
    • Speiser, B.; Stahl, H. Angew. Chem. 1995, 107, 1222-1224; Angew. Chem., Int. Ed. Engl. 1995, 34, 1086-1089.
    • (1995) Angew. Chem. , vol.107 , pp. 1222-1224
    • Speiser, B.1    Stahl, H.2
  • 35
    • 33748225144 scopus 로고
    • Speiser, B.; Stahl, H. Angew. Chem. 1995, 107, 1222-1224; Angew. Chem., Int. Ed. Engl. 1995, 34, 1086-1089.
    • (1995) Angew. Chem., Int. Ed. Engl. , vol.34 , pp. 1086-1089
  • 44
    • 1542408571 scopus 로고    scopus 로고
    • note
    • 0/+ + DMF (19) as the second solvent exchanges in either oxidation state. Other general definitions are given in note 32.
  • 53
    • 85086288115 scopus 로고    scopus 로고
    • note
    • -1, α = 0.42.
  • 59
    • 1542617867 scopus 로고    scopus 로고
    • In ref 80, p 158
    • In ref 80, p 158.
  • 63
    • 1542408572 scopus 로고    scopus 로고
    • In ref 81, 732
    • In ref 81, p 732.
  • 65
    • 85086290780 scopus 로고    scopus 로고
    • 4: Eichhorn, E.; Speiser, B.; et. al., manuscript in preparation.
    • 4: Eichhorn, E.; Speiser, B.; et. al., manuscript in preparation.
  • 71
    • 1542617863 scopus 로고    scopus 로고
    • note
    • 2: Eichhorn, E.; Rieker, A.; Speiser, B., manuscript in preparation.
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    • In ref 81, 44
    • In ref 81, p 44.
  • 73
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    • Further experiments to elucidate this effect in the present systems are currently under way
    • Further experiments to elucidate this effect in the present systems are currently under way.
  • 80
    • 85086289046 scopus 로고    scopus 로고
    • - shows that DMF is coordinated via the oxygen atom: see ref 36
    • - shows that DMF is coordinated via the oxygen atom: see ref 36.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.