Quantitation of oleuropein in virgin olive oil by ionspray mass spectrometry-selected reaction monitoring

Journal of Agricultural and Food Chemistry

Volumn 47, Issue 10, 1999, Pages 4156-4160

  Perri, Enzo ^a   Raffaelli, Andrea ^b   Sindona, Giovanni ^c  

^a Ist Sperimentale per l'Olivicoltura   (Italy)

^b UNIVERSITY OF PISA   (Italy)

^c UNIVERSITY OF CALABRIA   (Italy)

Author keywords

Ionspray mass spectrometry selected reaction monitoring (SRM); Oleuropein; Quantitative assay of oleuropein; Virgin olive oil

Indexed keywords

GLUCOSIDE; OLEUROPEIN; OLIVE OIL; PYRAN DERIVATIVE; SCAVENGER; VEGETABLE OIL;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HUMAN; ION MONITORING; MASS SPECTROMETRY; NUTRITIONAL VALUE; PARTITION COEFFICIENT; SOLUBILITY; SPECTRAL SENSITIVITY;

FREE RADICAL SCAVENGERS; HUMANS; MASS SPECTROMETRY; NUTRITIVE VALUE; PLANT OILS; PYRANS;

EID: 0000252427     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf981161d     Document Type: Article

References (17)

1. Bruins, A. P.; Weidolph, L. O. G.; Henion, J. D. Determination of sulfonated azo dyes by liquid chromatography/atmospheric pressure ionization mass spectrometry. Anal. Chem. 1987, 59, 2647-2652.
2. Busch, K. L.; Glish, G. L.; McLuckey, S. A. Mass Spectrometry / Mass Spectrometry: Techniques and Applications of Tandem Mass Spectrometry; VCH: New York, 1988.
3. Chimi, H.; Cillard, J.; Cillard, P.; Rahmani, M. Peroxyl and hydroxyl radical scavenging activity of some natural phenolic antioxidants. J. Am. Oil Chem. Soc. 1991, 68, 307-311.
4. De Nino, A.; Perri, E.; Lombardo, N.; Procopio, A.; Raffaelli, A.; Sindona, G. Direct identification of phenolic glucosides from olive leaves extracts by atmospheric pressure ionization tandem mass spectrometry. J. Mass Spectrom. 1997, 32, 533-541.
5. De Nino, A.; Mazzotti, F.; Morrone, S. P.; Perri, E.; Raffaelli, A.; Sindona, G. Characterisation of cassanese olive cultivar through the identification of new trace components by ionspray tandem mass spectrometry. J. Mass Spectrom. 1999, 34, 10-16.
6. Fleming, H. P.; Walter, W. M., Jr.; Etchells, L. L. Antimicrobial properties of oleuropein and products of its hydrolysis from green olives. Appl. Microbiol. 1973, 26, 777-776.
7. Gariboldi, G.; Jommi, G.; Verotta, I. Phytochemistry 1986, 25, 865-869.
8. Huang, E. C.; Wachs, J.; Conboy, J.; Henion, J. D. Anal. Chem. 1990, 62, 713A-725A.
9. Laubli, M.; Bruttel, P. A. Determination of oxidative stability of fats and oils: comparison between the active oxygen method (AOCS cd 12-57) and the Rancimat method. J. Assoc. Oil Chem. Soc. 1986, 63, 792-795.
10. 13C NMR characterization of new oleuropein aglycones. J. Chem. Soc., Perkin Trans. 1 1995, 1519-1523.
11. McLafferty, F. W. Tandem Mass spectrometry (MS/MS): a promising new analytical tecnique for specific component determination in complex mixtures. Acc. Chem. Res. 1980, 13, 33-39.
12. Mann, M.; Shen, S.; Fenn, J. B. Electrospray Mass Spectrometry. In Mass Spectrometry in the Biological Sciences: A tutorial; Gross, M. L., Eds.; Kluwer: Dordrecht, The Netherlands, 1992.
13. Montedoro, G.; Servili, M.; Baldioli, M.; Miniati, E. Simple and hydrolizable compounds in virgin olive oil. 1. Their extraction, separation and quantitative and semiquantitative evaluation by HPLC. J. Agric. Food Chem. 1992, 40 ,1571-1576.
14. Montedoro, G.; Servili, M.; Baldioli, M.; Selvaggini, R.; Miniati, E.; Macchioni, A. Simple and hydrolizable compounds in virgin olive oil. 3. Spectroscopic characterizations of the secoiridoid derivatives. J. Agric. Food Chem. 1993, 41, 2228-2234.
15. Panizzi, L.; Scarpati, M. L.; Oriente, G. Costituzione della Oleuropeina, glucoside amaro e ad azione ipotensiva dell'olivo. Gazz. Chim. Ital. 1960, 90, 1449-1485.
16. Perri E. Sensitive and Selective Determination of Oleuropein in Virgin Olive Oil by Ionspray Ionization Mass Spectrometry. Presented at the 2nd MS-PHARMADAY, Siena, Italy, July 1996; paper C-24.
17. Visioli, F.; Bellosta, S.; Galli, C. Oleuropein, the bitter principle of olives, enhances nitric oxide production by mouse macrophages. Life Sci. 1998, 62, 541-546.