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Volumn 36, Issue 3, 1997, Pages 362-365

Electron Transfer. 133. Copper Catalysis in the Sulfite Reduction of Peroxynitrite

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EID: 0000252236     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960907r     Document Type: Article
Times cited : (21)

References (55)
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    • Sponsorship of this work by the National Science Foundation (Grant 9414113) is gratefully acknowledged.
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    • Reactions at lower pH's, which proceed at rates measurable by flow methods, were not examined in detail since reagents appeared to become irreproducibly contaminated, on mixing, with traces of dissolved copper arising from corroded surfaces of the metal valves in our flow system.
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    • . reaction (13). Although we cannot rule out such a dimerization as a minor path, a major contribution of this type would not be compatible with what is observed as the stoic biometry approaches 1:1.


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