Octahedral Group 4 Metal Complexes That Contain Amine, Amido, and Aminopyridinato Ligands: Synthesis, Structure, and Application in α-Olefin Oligo- and Polymerization

Inorganic Chemistry

Volumn 35, Issue 23, 1996, Pages 6742-6745

  Fuhrmann, Hans ^a   Brenner, Simon ^a   Arndt, Perdita ^a   Kempe, Rhett ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000250409     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960182r     Document Type: Article

References (45)

1. Among the large numbers of publications in this field we would like to mention just three of the latest review articles: Brintzinger, H.-H.; Fischer, D; Mülhaupt, Rolf; Rieger, B; Waymouth, R Angew. Chem. 1995, 107, 1255. Aulbach, M.; Küber, F. Chem. Unserer Zeit 1994, 28, 197. Möhring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1.
2. Among the large numbers of publications in this field we would like to mention just three of the latest review articles: Brintzinger, H.-H.; Fischer, D; Mülhaupt, Rolf; Rieger, B; Waymouth, R Angew. Chem. 1995, 107, 1255. Aulbach, M.; Küber, F. Chem. Unserer Zeit 1994, 28, 197. Möhring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1.
3. Among the large numbers of publications in this field we would like to mention just three of the latest review articles: Brintzinger, H.-H.; Fischer, D; Mülhaupt, Rolf; Rieger, B; Waymouth, R Angew. Chem. 1995, 107, 1255. Aulbach, M.; Küber, F. Chem. Unserer Zeit 1994, 28, 197. Möhring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1.
4. Kaminsky, W.; Spiehl, R. Makromol. Chem. 1989, 190, 515. Kaminsky, W.; Bark, A.; Arndt, M. Macromol. Chem. Macromol. Symp. 1991, 47, 83. Kaminsky, W.; Bark, A. Polym. Int. 1992, 28, 251.
5. Kaminsky, W.; Spiehl, R. Makromol. Chem. 1989, 190, 515. Kaminsky, W.; Bark, A.; Arndt, M. Macromol. Chem. Macromol. Symp. 1991, 47, 83. Kaminsky, W.; Bark, A. Polym. Int. 1992, 28, 251.
6. Kaminsky, W.; Spiehl, R. Makromol. Chem. 1989, 190, 515. Kaminsky, W.; Bark, A.; Arndt, M. Macromol. Chem. Macromol. Symp. 1991, 47, 83. Kaminsky, W.; Bark, A. Polym. Int. 1992, 28, 251.
7. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1991, 113, 6270. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1993, 115, 91. Kesti, M. R.; Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1992, 114, 9679.
8. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1991, 113, 6270. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1993, 115, 91. Kesti, M. R.; Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1992, 114, 9679.
9. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1991, 113, 6270. Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1993, 115, 91. Kesti, M. R.; Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1992, 114, 9679.
10. Yasuda, H.; Yamamoto, H.; Yokota, K.; Miyake, S.; Nakamura, A. J. Am. Chem. Soc. 1992,114, 4908. Yasuda, H.; Furo, N.; Yamamoto, H.; Nakamura, A.; Miyake, S.; Kibino, N. Macromolecules 1992, 25, 5115. Yasuda, H.; Yamamoto, H.;Yamashita, M.; Yokota, K.; Nakamura, A.; Miyake, S.; Kai, Y.; Tanehisa, N. Macromolecules 1993, 26, 7134.
11. Yasuda, H.; Yamamoto, H.; Yokota, K.; Miyake, S.; Nakamura, A. J. Am. Chem. Soc. 1992,114, 4908. Yasuda, H.; Furo, N.; Yamamoto, H.; Nakamura, A.; Miyake, S.; Kibino, N. Macromolecules 1992, 25, 5115. Yasuda, H.; Yamamoto, H.;Yamashita, M.; Yokota, K.; Nakamura, A.; Miyake, S.; Kai, Y.; Tanehisa, N. Macromolecules 1993, 26, 7134.
12. Yasuda, H.; Yamamoto, H.; Yokota, K.; Miyake, S.; Nakamura, A. J. Am. Chem. Soc. 1992,114, 4908. Yasuda, H.; Furo, N.; Yamamoto, H.; Nakamura, A.; Miyake, S.; Kibino, N. Macromolecules 1992, 25, 5115. Yasuda, H.; Yamamoto, H.;Yamashita, M.; Yokota, K.; Nakamura, A.; Miyake, S.; Kai, Y.; Tanehisa, N. Macromolecules 1993, 26, 7134.
13. Kakugo, M.; Miyatake, T.; Mizunuma, K. Chem. Express 1987, 2, 445. Miyatake, T.; Mizunuma, K.; Seki, Y; Kakugo, M. Makromol. Chem., Rapid Commun. 1989, 10, 349. Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203. Schaverien, C. J.; van der Linden, A. J.; Orpen, A. G. Am. Chem. Soc., Polym. Div., Polym. Prep. 1994, 35, 672. van der Linden, A. J.; Schaverien, C. J.; Meijboom, M.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
14. Kakugo, M.; Miyatake, T.; Mizunuma, K. Chem. Express 1987, 2, 445. Miyatake, T.; Mizunuma, K.; Seki, Y; Kakugo, M. Makromol. Chem., Rapid Commun. 1989, 10, 349. Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203. Schaverien, C. J.; van der Linden, A. J.; Orpen, A. G. Am. Chem. Soc., Polym. Div., Polym. Prep. 1994, 35, 672. van der Linden, A. J.; Schaverien, C. J.; Meijboom, M.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
15. Kakugo, M.; Miyatake, T.; Mizunuma, K. Chem. Express 1987, 2, 445. Miyatake, T.; Mizunuma, K.; Seki, Y; Kakugo, M. Makromol. Chem., Rapid Commun. 1989, 10, 349. Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203. Schaverien, C. J.; van der Linden, A. J.; Orpen, A. G. Am. Chem. Soc., Polym. Div., Polym. Prep. 1994, 35, 672. van der Linden, A. J.; Schaverien, C. J.; Meijboom, M.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
16. Kakugo, M.; Miyatake, T.; Mizunuma, K. Chem. Express 1987, 2, 445. Miyatake, T.; Mizunuma, K.; Seki, Y; Kakugo, M. Makromol. Chem., Rapid Commun. 1989, 10, 349. Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203. Schaverien, C. J.; van der Linden, A. J.; Orpen, A. G. Am. Chem. Soc., Polym. Div., Polym. Prep. 1994, 35, 672. van der Linden, A. J.; Schaverien, C. J.; Meijboom, M.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
17. Kakugo, M.; Miyatake, T.; Mizunuma, K. Chem. Express 1987, 2, 445. Miyatake, T.; Mizunuma, K.; Seki, Y; Kakugo, M. Makromol. Chem., Rapid Commun. 1989, 10, 349. Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203. Schaverien, C. J.; van der Linden, A. J.; Orpen, A. G. Am. Chem. Soc., Polym. Div., Polym. Prep. 1994, 35, 672. van der Linden, A. J.; Schaverien, C. J.; Meijboom, M.; Ganter, C.; Orpen, A. G. J. Am. Chem. Soc. 1995, 117, 3008.
18. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 1827. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 2106. Canich, J. M.; Turner, H. W. PCT Int. Appl. WO 92/12612 filing date Dec 26, 1991.
19. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 1827. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 2106. Canich, J. M.; Turner, H. W. PCT Int. Appl. WO 92/12612 filing date Dec 26, 1991.
20. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 1827. Flores, J. C.; Chien, J. C. W.; Rausch, M. D. Organometallics 1995, 14, 2106. Canich, J. M.; Turner, H. W. PCT Int. Appl. WO 92/12612 filing date Dec 26, 1991.
21. 2/MAO has been claimed to polymerize propene to i-PP (90% m diads) Canich, J. M.; Turner, H. W. PCT Int. Appl. WO 92/12612 filing date Dec 26, 1991. The benzamidinato catalyst systems reported by Rausch et al. (see ref 6) are not active in propene polymerization.
22. Aminopyridinato ligands are deprotonated 2-aminopyridines which are coordinated as strained bidentate ligands (anionic ligands that donate up to 1 V six electrons to the metal). Edema, J. J. H.; Gambarotta, S.; Meetsma, A; Spek, A. L.; Veldman, N. Inorg. Chem.1991, 30, 2062. Calhorda, M. J.; Carrondo, M. A. A. F. De C. T.; Gomes da Costa, R.; Dias, A. R.; Duarte, M. T. L. S.; Hursthouse, M. B. J. Organomet. Chem. 1987, 320, 53. Chakravarty, A. R.; Cotton, F. A.; Shamshoum, E. S. Inorg. Chim. Acta 1984, 86, 5.
23. Aminopyridinato ligands are deprotonated 2-aminopyridines which are coordinated as strained bidentate ligands (anionic ligands that donate up to 1 V six electrons to the metal). Edema, J. J. H.; Gambarotta, S.; Meetsma, A; Spek, A. L.; Veldman, N. Inorg. Chem.1991, 30, 2062. Calhorda, M. J.; Carrondo, M. A. A. F. De C. T.; Gomes da Costa, R.; Dias, A. R.; Duarte, M. T. L. S.; Hursthouse, M. B. J. Organomet. Chem. 1987, 320, 53. Chakravarty, A. R.; Cotton, F. A.; Shamshoum, E. S. Inorg. Chim. Acta 1984, 86, 5.
24. Aminopyridinato ligands are deprotonated 2-aminopyridines which are coordinated as strained bidentate ligands (anionic ligands that donate up to 1 V six electrons to the metal). Edema, J. J. H.; Gambarotta, S.; Meetsma, A; Spek, A. L.; Veldman, N. Inorg. Chem.1991, 30, 2062. Calhorda, M. J.; Carrondo, M. A. A. F. De C. T.; Gomes da Costa, R.; Dias, A. R.; Duarte, M. T. L. S.; Hursthouse, M. B. J. Organomet. Chem. 1987, 320, 53. Chakravarty, A. R.; Cotton, F. A.; Shamshoum, E. S. Inorg. Chim. Acta 1984, 86, 5.
25. Sheldrick, G. M. Acta Crystallogr. Sect. 1990, A46, 467.
26. Sheldrick G. M. SHELXL-93:A program for crystal structure refinement; University of Göttingen: Göttingen Germany, 1993.
27. Kempe, R.; Arndt, P. Inorg. Chem. 1996, 35, 2644.
28. Phillion, D. P.; Neubauer, R.; Andrew, S. S. J. Org. Chem. 1986, 51, 1610.
29. Benzinger, E.; Kornicker, W. Chem. Ber. 1961, 94, 2263.
30. Kempe, R.; Brenner, S.; Arndt, P. Organometallics 1996, 15, 1071.
31. Engelhardt, L. M.; Jacobsen, G. E.; Junk, P. C.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1988, 1011. Engelhardt, L. M.; Jacobsen, G. E.; Patalinghug, W. C.; Skelton, B. W.; Raston, C. L.; White, A. H. J. Chem. Soc., Dalton Trans. 1991, 2859.
32. Engelhardt, L. M.; Jacobsen, G. E.; Junk, P. C.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1988, 1011. Engelhardt, L. M.; Jacobsen, G. E.; Patalinghug, W. C.; Skelton, B. W.; Raston, C. L.; White, A. H. J. Chem. Soc., Dalton Trans. 1991, 2859.
33. Kempe, R.; Brenner, S; Arndt, P. Z. Anorg. Allg. Chem. 1996, 621, 2021.
34. Roesky, H. W.; Meller, B.; Noltemeyer, M.; Schmidt, H.-G.; Scholz, U.; Sheldrick, G. M. Chem. Ber., 1988, 121, 1403. Edelmann, F. T. Coord. Chem. Rev. 1994, 137, 403.
35. Roesky, H. W.; Meller, B.; Noltemeyer, M.; Schmidt, H.-G.; Scholz, U.; Sheldrick, G. M. Chem. Ber., 1988, 121, 1403. Edelmann, F. T. Coord. Chem. Rev. 1994, 137, 403.
36. Christensen, A. N.; Grand, A.; Lehmann, M. S.; Cox, D. E. Acta Chem. Scand. 1990, 44, 103. Brand, H.; Arnold, J. Organometallics 1993, 12, 3655.
37. Christensen, A. N.; Grand, A.; Lehmann, M. S.; Cox, D. E. Acta Chem. Scand. 1990, 44, 103. Brand, H.; Arnold, J. Organometallics 1993, 12, 3655.
38. Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1982, 142. De Angelis, S.; Solari, E.; Gallo, E.; Roriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520.
39. Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1982, 142. De Angelis, S.; Solari, E.; Gallo, E.; Roriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520.
40. Ewen, J. A. J. Am. Chem. Soc. 1984, 106, 6355. Kaminsky, W. Angew. Makromol. Chem. 1986, 145/146, 149. Eshuis, J. J. W.; Tan, Y. Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277.
41. Ewen, J. A. J. Am. Chem. Soc. 1984, 106, 6355. Kaminsky, W. Angew. Makromol. Chem. 1986, 145/146, 149. Eshuis, J. J. W.; Tan, Y. Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277.
42. Ewen, J. A. J. Am. Chem. Soc. 1984, 106, 6355. Kaminsky, W. Angew. Makromol. Chem. 1986, 145/146, 149. Eshuis, J. J. W.; Tan, Y. Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277.
43. Barber, J. J.; Willis, C.; Whiteside, G. M. J. Org. Chem. 1979, 44, 3603. Dzhemilev, V. M.; Ibragimov, A. G.; Vostrikova, O. S.; Tolstikov, G. A.; Zelenova, L. M. Izv. Akad. Nauk SSSR, Ser. Khim. 1981, 361. Dzhemilev, V. M.; Vostrikova, O. S. J Organomet. Chem. 1985, 285, 431.
44. Barber, J. J.; Willis, C.; Whiteside, G. M. J. Org. Chem. 1979, 44, 3603. Dzhemilev, V. M.; Ibragimov, A. G.; Vostrikova, O. S.; Tolstikov, G. A.; Zelenova, L. M. Izv. Akad. Nauk SSSR, Ser. Khim. 1981, 361. Dzhemilev, V. M.; Vostrikova, O. S. J Organomet. Chem. 1985, 285, 431.
45. Barber, J. J.; Willis, C.; Whiteside, G. M. J. Org. Chem. 1979, 44, 3603. Dzhemilev, V. M.; Ibragimov, A. G.; Vostrikova, O. S.; Tolstikov, G. A.; Zelenova, L. M. Izv. Akad. Nauk SSSR, Ser. Khim. 1981, 361. Dzhemilev, V. M.; Vostrikova, O. S. J Organomet. Chem. 1985, 285, 431.