Reversible cyclometalation of silyl ligands. First X-ray structure of an iridium(I) silyl that is not stabilized by chelation

Organometallics

Volumn 15, Issue 15, 1996, Pages 3317-3322

  Aizenberg, Michael ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000243269     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960214i     Document Type: Article

References (37)

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3. Reviews: (a) Parshall, G. W. Acc. Chem. Res. 1970, 3, 139. (b) Bruce, M. I. Angew. Chem., Int. Ed. Engl. 1977, 16, 73. (c) Ryabov, A. D. Chem. Rev. 1990, 90, 403.
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31. Information on Ir-Si bond lengths in five- and six-coordinate complexes of Ir(III) can be found in: (a) Tilley, T. D. In The Silicon-Heteroatom Bond; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1991; pp 264, 343. (b) Goikhman, R.; Aizenberg, M.; Kraatz, H.-B.; Milstein, D. J. Am. Chem. Soc. 1995, 117, 5865. See also refs 3b, 11d, and 12.
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