메뉴 건너뛰기




Volumn 101, Issue 15, 1997, Pages 2833-2840

Spectroscopy and kinetics of singlet perfluoro-4-biphenylnitrene and singlet perfluorophenylnitrene

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000235516     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp963139y     Document Type: Article
Times cited : (84)

References (35)
  • 1
    • 0002120722 scopus 로고
    • Photochemistry of Phenyl Azide
    • Schuster, G. B.; Platz, M. S. Photochemistry of Phenyl Azide. Adv. Photochem. 1992, 17, 69-143.
    • (1992) Adv. Photochem. , vol.17 , pp. 69-143
    • Schuster, G.B.1    Platz, M.S.2
  • 9
    • 0003673645 scopus 로고
    • Platz, M. S., Ed.; Plenum: New York
    • -1. This raises the barrier to rearrangement of singlet phenylnitrene to 6 kcal/mol upon reanalysis of the data. Slow ISC of singlet phenylnitrene, relative to phenylcarbene, is a consequence of a large singlet-triplet gap of the nitrene and the fact that the singlet nitrene has an open shell configuration (ref 7).
    • (1990) Kinetics and Spectroscopy of Carbenes and Biradicals
    • Platz, M.S.1    Maloney, V.M.2
  • 10
    • 0030988972 scopus 로고    scopus 로고
    • Borden, W. T.; Karney, W. J. Am. Chem. Soc. 1997, 119, 1378-1387. In fact, fluorinated azirines have recently been detected in matrices following photolysis of polyfluorinated triplet aryl nitrenes. See: Morawietz, J.; Sander, W. J. Org. Chem. 1996, 61, 4351.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 1378-1387
    • Borden, W.T.1    Karney, W.2
  • 11
    • 0001413531 scopus 로고    scopus 로고
    • Borden, W. T.; Karney, W. J. Am. Chem. Soc. 1997, 119, 1378-1387. In fact, fluorinated azirines have recently been detected in matrices following photolysis of polyfluorinated triplet aryl nitrenes. See: Morawietz, J.; Sander, W. J. Org. Chem. 1996, 61, 4351.
    • (1996) J. Org. Chem. , vol.61 , pp. 4351
    • Morawietz, J.1    Sander, W.2
  • 17
    • 85033177824 scopus 로고    scopus 로고
    • note
    • R and its associated activation parameters should be associated with cyclization to azirine 5 (ref 6).
  • 30
    • 85033166848 scopus 로고
    • Ph.D. Thesis, The Ohio State University
    • (a) Vander Stouw, G. Ph.D. Thesis, The Ohio State University, 1964.
    • (1964)
    • Vander Stouw, G.1
  • 34
    • 85033181167 scopus 로고    scopus 로고
    • Private communication
    • Private communication from Drs. Borden and Karney.
    • Borden1    Karney2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.