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Thus, the rate should increase with increasing exergonicity to some maximum, which is characteristic of the system, and then decrease with further increases in exergonicity. The latter condition defines the “inverted” region
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The Marcus theory13 predicts that the rate of an outer-sphere electron transfer is a quadratic function of the reaction Gibbs energy. Thus, the rate should increase with increasing exergonicity to some maximum, which is characteristic of the system, and then decrease with further increases in exergonicity. The latter condition defines the “inverted” region.
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Parts of this work were described in a preliminary report. See:
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These rates have been confirmed by a mutual exchange of samples with the Arizona State group
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These rates have been confirmed by a mutual exchange of samples with the Arizona State group. There is no significant difference in the electron-transfer rates of III as compared with the molecule that Gust studied33 with the NH2 group replaced by a methyl group as in I.
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