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The Gaussian fits are believed to provide a good means for estimating the uncertainty in these experiments but may not represent the best model for fitting this type of data (Noy, A.; Lieber, C. M. unpublished results). For example, the Gaussian fit assumes a symmetric distribution of forces between ±∞, while all forces are >0.
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s = 54 nm
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1/2] where R is the tip radius. Hence, as the tip radius increases the contact area and number of intermolecular interactions will increase for a given applied load.
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note
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Adhesion and friction force measurements were made with samples composed of homogeneous long-chain alkylthiols which have crystalline structure (see ref 25). In the case of functional group imaging, SAMs terminating in a relatively bulky phenylazide group were used, and the desired terminal groups were subsequently attached photochemically. Though the same trend in friction is observed in these SAMs as with the simpler homogeneous monolayers, the same argument for crystalline structure cannot be made.
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note
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2O will be present on a surface even in inert atmosphere conditions).
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