A new layered aluminophosphate [Al2P4O16][C6H22N 4][C2H10N2] with 4.12-net porous sheets

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 13, 2000, Pages 1979-1980

  Wei, Bo ^a   Yu, Jihong ^a   Shi, Zhan ^a   Qiu, Shilun ^a   Li, Jiyang ^a  

^a Jilin University   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000216220     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b003153o     Document Type: Article

References (21)

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16. 4 (85wt% in water) was added dropwise to form a gel. Finally, 4.0 mL of TETA was added to the above mixture. The reaction mixture was further stirred until homogenous and then was sealed in a Teflon-lined stainless steel autoclave and heated at 185°C for 12 days under autogenous pressure. The resulting product containing pure large platelike single crystals of up to 1 mm was filtered and washed thoroughly with ethanol and deionized water, and dried at ambient temperature.
17. 2 = 0.0836, Data/restraints/parameters = 1679/0/227. Structural analysis was performed on a Siemens SMART CCD diffractometer using graphite-monochromated Mo-Kα radiation (λ(Mo-Kα) = 0.71073 Å). The data were collected at 20 ± 2°C. Data processing was accomplished with the SAINT processing program (SMART and SAINT (software packages), Siemens Analytical X-ray Instruments, Inc., Madison, WI, 1996.). Direct methods were used to solve the structure using the SHELXTL crystallographic software package (SHELXL, version 5.1; Siemens Industral Automation, Inc., 1997.). Hydrogen atoms were located by a difference Fourier map, and were added to the structure factor calculation. All non-hydrogen atoms were refined anisotropically. CCDC reference number 186/2002. See http://www.rsc.org/suppdata/dt/bO/b003153o/ for crystallographic files in .cif format.
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