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Volumn 103, Issue 20, 1981, Pages 6073-6083

Static and Dynamic Stereochemistry of Hexaethylbenzene and of Its Tricarbonylchromium, Tricarbonylmolybdenum, and Dicarbonyl(triphenylphosphine)chromium Complexes

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EID: 0000214175     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00410a015     Document Type: Article
Times cited : (199)

References (37)
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    • and references therein.
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    • MacNicol, D. D.; Hardy, A. D. U.; Wilson, D. R. Nature (London) 1977, 266, 611. MacNicol, D. D.; McKendrick, J. J.; Wilson, D. R. Chem. Soc. Rev. 1978, 65. Hardy, A. D. U.; MacNicol, D. D.; Swanson, S.; Wilson,D. R. Tetrahedron Lett. 1978, 3579. Hardy, A. D. U.; MacNicol, D. D.;Wilson, D. R. J. Chem. Soc., Perkin Trans. 2 1979, 1011. Hardy, A. D. U.;MacNicol, D. D.; Swanson, S.; Wilson, D. R. Tetrahedron. 1980, 999. Freer, A.;Gilmore, C. J.; MacNicol, D. D.; Wilson, D. R. Tetrahedron Lett. 1980,1159.
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    • MacNicol, D.D.1    Hardy, A.D.U.2    Wilson, D.R.3
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    • Appropriately substituted hexaphenylbenzenes may also be includedin this class. 1977, 99, 6980. Gust, D.;Patton, A. Tetrahedron.
    • Appropriately substituted hexaphenylbenzenes may also be includedin this class. See: Gust, D. J. Am. Chem. Soc. 1977, 99, 6980. Gust, D.;Patton, A. Tetrahedron. 1978, 100, 8175.
    • (1978) Am. Chem. Soc. , vol.100 , pp. 8175
    • Gust, D.J.1
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    • For recent reviews of the EFF method, 1976, 81. Ermer, O. Struct.Bonding (Berlin) 1976, 27,161. Allinger, N. L. Adv. Phys. Org. Chem. 1976,13,1. Aliona, C.; Faber, D. H. Fortschr. Chem. Forsch. 1974, 45, 1. Seealso: Mislow, K.; Dougherty, D. A.; Hounshell, W. D. Bull. Soc. Chim. Belg.
    • For recent reviews of the EFF method, see: Dunitz, J. D.; Bürgi, H.B. MTP Int. Rev. Sci. Org. Chem., Ser. One 1976, 81. Ermer, O. Struct.Bonding (Berlin) 1976, 27,161. Allinger, N. L. Adv. Phys. Org. Chem. 1976,13,1. Aliona, C.; Faber, D. H. Fortschr. Chem. Forsch. 1974, 45, 1. Seealso: Mislow, K.; Dougherty, D. A.; Hounshell, W. D. Bull. Soc. Chim. Belg. 1978, 87, 555.
    • (1978) MTP Int. Rev. Sci. Org. Chem., Ser. One , vol.87 , pp. 555
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    • Andose, J. D. et al. QCPE 1978, 10, 348.
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    • 1965, 4, 1314. Rees, B.;Coppens, P. Acta Crystallogr., Sect. B
    • Bailey, M. F.; Dahl, L. F. Inorg. Chem. 1965, 4, 1314. Rees, B.;Coppens, P. Acta Crystallogr., Sect. B 1973, B29, 2516.
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    • Bailey, M.F.1    Dahl, L.F.2
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    • The other conformationis generated by a 60° twist of the M(CO)3 moiety.
    • Only one is shown for E(3) and S(3) in Figure 6. The other conformationis generated by a 60° twist of the M(CO)3 moiety.
    • Only one is shown for E(3) and S(3) in Figure 6.
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    • pp 140-142.
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    • in s-1 (temp, K), are 18 (223), 42 (232),76 (237), 230 (246), 2150 (269), and 2750 (273) for 2 and are 2 (205), 40(231), 77 (234), 185 (244), 350 (250), 600 (254), and 643 (256) for 3.(63) Harris, R. K.; Newman, R. H. J. Magn. Reson.
    • Experimental rate constants, in s-1 (temp, K), are 18 (223), 42 (232),76 (237), 230 (246), 2150 (269), and 2750 (273) for 2 and are 2 (205), 40(231), 77 (234), 185 (244), 350 (250), 600 (254), and 643 (256) for 3.(63) Harris, R. K.; Newman, R. H. J. Magn. Reson. 1976, 24, 449.
    • (1976) Experimental rate constants , vol.24 , pp. 449


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