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A literature search produced several thousand references on the general topic of sensors for the period of 1991-1996. For example, see: (a) Persaud, K.; Dodd, G. H. Nature (London) 1982, 299, 352. (b) Shurmer, H. V. Anal. Proc. Inc. Anal. Comm. 1994, 31, 39. (c) The U.S. EPA Environmental Technology Initiative for FY 1994 included monitoring VOCs as a critical need.
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We have observed that dissolution of a solid film on the surface of the ATR crystal causes a decrease in absorbance. This effect was previously attributed to a lower concentration of sample in contact with the crystal surface. See: (a) Ingle, J. D., Jr.; Crouch, S. R. Spectrochemical Analysis; Prentice Hall: Englewood Cliffs, NJ, 1988; pp 429-434. (b) Exstrom, C. L. Ph.D. Dissertation, University of Minnesota, 1995. Footnote 19 in ref 4b incorrectly describes this process as leading to an increase in absorbance.
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We have observed that dissolution of a solid film on the surface of the ATR crystal causes a decrease in absorbance. This effect was previously attributed to a lower concentration of sample in contact with the crystal surface. See: (a) Ingle, J. D., Jr.; Crouch, S. R. Spectrochemical Analysis; Prentice Hall: Englewood Cliffs, NJ, 1988; pp 429-434. (b) Exstrom, C. L. Ph.D. Dissertation, University of Minnesota, 1995. Footnote 19 in ref 4b incorrectly describes this process as leading to an increase in absorbance.
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