Contributions to the chemistry of brominetrifluoride. Part 2. Bis(pentafluorophenyl)bromonium cations with weak nucleophilic fluoroelementate anions

European Journal of Solid State and Inorganic Chemistry

Volumn 33, Issue 9, 1996, Pages 841-853

  Frohn, H J ^a   Giesen, M ^a   Welting, D ^a   Henkel, G ^a  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000171709     PISSN: 09924361     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (22)

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2. a) G. A. OLAH, Halonium Ions, Wiley, New York, 1975, p. 88;
3. b) G. F. KOSER, Halonium Ions, in The Chemistry of Functional Groups, Ed. S. PATAI and Z. RAPPOPORT, Wiley, Chichester, 1983, Chapter 25, p. 1265.
4. + (E = element of group 17 and 18);
5. b) H. J. FROHN, M. GIESEN and D. WELTING, 11th European Fluorine Symp., Bled, Slovenia, Sept. 1995, abstract p. 30, Bis(pentafluorophenyl)bromonium Compounds;
6. c) W. BREUER and H. J. FROHN, Z. Anorg. Allg. Chem., 1992, 611, p. 85;
7. d) H. J. FROHN and S. JAKOBS, J. Chem. Soc.. Chem. Commun., 1989, p. 625.
8. a) H. J. FROHN, Nachr. Chem. Tech. Lab., 1993, 41, p. 956;
9. b) V. V. BARDIN, T. FIEFHAUS, H. J. FROHN, A. KLOSE, R. NIELINGER, A. PRIWITZER and T. SCHROER, J. Fluorine Chem., 1995, 71, p. 183;
10. c) S. DATSENKO, N. IGNAT'EV, P. BARTHEN, H. J. FROHN, T. SCHOLTEN, T. SCHROER and D. WELTING, 11th European Fluorine Symp., Bled, Slovenia, Sept. 1995, abstract p. 122, Electrochemical Reduction of Pentafluorophenyliodonium, -diazonium and -xenonium Salts.
11. H. J. FROHN and M. GIESEN, J. Fluorine Chem., 1984, 24, p. 9.
12. a) T. W. BASTOCK, M. E. HARLEY, A. E. PEDLER and J. C. TATLOW, J. Fluorine Chem., 1975, 6, p. 331;
13. b) V. V. BARDIN, G. G. FURIN and G. G. YAKOBSON, J. Fluorine Chem., 1983, 23, p. 67.
14. R. J. GILLESPIE, Molecular Geometry, Van Nostrand-Reinhold, New York, 1972.
15. H. J. FROHN and V. V. BARDIN, Z. Naturforsch., 1996, 51b, in print.
16. a) D. NAUMANN, H. BUTLER, R. GNANN and W. TYRRA, Inorg. Chem., 1993, 32, p. 861;
17. + with anionic nucleophiles.
18. a) H. J. FROHN, S. JAKOBS and G. HENKEL, Angew. Chem., 1989, 101, p. 1534;
19. b) H. J. Frohn, T. Schroer and G. Henkel, Z. Naturforsch. 50 b, 1995, p. 1799.
20. Details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen 2, quoting the number CSD-59305, the names of the authors and the journal citation.
21. A. BONDI, J. Phys. Chem., 1964, 68, p. 441.
22. 5Br.