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33745483409
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The choice within the wide range of chlorides and acetylacetonates of transition metals available on the market was governed by their availability in our stockrooms, or their low price, or obtaining them as a gift.
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The choice within the wide range of chlorides and acetylacetonates of transition metals available on the market was governed by their availability in our stockrooms, or their low price, or obtaining them as a gift.
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33745486646
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[10] are underestimated since conversions and yields are calculated on the isolated compounds; these quantities are inherently lower than those present in the reaction mixtures. In fact, we have not de-tected compounds, other than 1 and 2, by TLC analysis of the crude mixtures when the selectivities corresponding to these runs were superior to 86%.
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[10] are underestimated since conversions and yields are calculated on the isolated compounds; these quantities are inherently lower than those present in the reaction mixtures. In fact, we have not de-tected compounds, other than 1 and 2, by TLC analysis of the crude mixtures when the selectivities corresponding to these runs were superior to 86%.
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22
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33745489722
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The analysis of the NMR spectra showed that 3 was a mixture of diastereoisomers.
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The analysis of the NMR spectra showed that 3 was a mixture of diastereoisomers.
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25
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33745484421
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Heating a mixture of 1, lithium chloride, sodium carbonate and catalytic amounts of both Adogen 464 and palladium chloride in DCE also induced the formation of 3: unpublished results.
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Heating a mixture of 1, lithium chloride, sodium carbonate and catalytic amounts of both Adogen 464 and palladium chloride in DCE also induced the formation of 3: S. Aït-Mohand, unpublished results.
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33745497978
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13C chemical shifts are in agreement with those calculated using Chemintosh program.
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13C chemical shifts are in agreement with those calculated using Chemintosh program.
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