Synthesis and characterization of tungsten alkenyl-carbyne and alkenyl-ketenyl complexes containing dithio ligands. X-ray crystal structure and MO analyses of [(dppe){κ3(S,C,S)-S2CPCy 3}W≡CCH=C(CH2)3CH2][BF 4]

Organometallics

Volumn 16, Issue 19, 1997, Pages 4099-4108

  Zhang, Lei ^a   Gamasa, M Pilar ^a   Gimeno, José ^a   Galindo, Agustin ^b   Mealli, Carlo ^c   Lanfranchi, Maurizio ^d   Tiripicchio, Antonio ^d  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF SEVILLE   (Spain)

^c Ist Per lo Stud della S   (Italy)

^d UNIVERSITY OF PARMA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000163081     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970291t     Document Type: Article

References (59)

1. Fischer, E. O.; Kreis, G.; Kreiter, C. G.; Müller, J.; Huttner, G.; Lorenz, H. Angew. Chem. 1973, 85, 618; Angew. Chem., Int. Ed. Engl. 1973, 12, 564.
2. Fischer, E. O.; Kreis, G.; Kreiter, C. G.; Müller, J.; Huttner, G.; Lorenz, H. Angew. Chem. 1973, 85, 618; Angew. Chem., Int. Ed. Engl. 1973, 12, 564.
3. (a) Fischer, H.; Hofmann, P; Kreissl, F. R.; Schrock, R. R.; Schubert, U.; Weiss, K. Carbyne Complexes; VCH Publishers: Weinheim, Germany, 1988.
4. (b) Mayr, A. Comm. Inorg. Chem. 1990, 10, 227.
5. (c) Mayr, A.; Hoffmeister, H. Adv. Organomet. Chem. 1991, 32, 227.
6. (d) Mayr, A.; Bastos, C. Prog. Inorg. Chem. 1992, 40, 1.
7. (e) Transition Metal Carbyne Complexes; Kluwer Academic Publishers: Dordrecht, Boston, London, 1993.
8. (f) Engel, P. F.; Pfeffer, M. Chem. Rev. 1995, 95, 2281.
9. 3] (M = Mo, W): Hart, I. J.; Hill, A. F.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1989, 2261.
10. 3] (M = Mo, W): Hart, I. J.; Hill, A. F.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1989, 2261.
11. 2)Ph]: see ref 3a.
12. (c) A trinuclear cluster of tungsten and rhenium containing an alkenyl-carbyne group has also been described: Peng. J. J.; Peng, S. M.; Lee, G. H.; Chi, Y. Organometallics 1995, 14, 626.
13. Zhang, L.; Gamasa, M. P.; Gimeno, J.; Carbajo, R. J.; López-Ortiz, F.; Lanfranchi, M.; Tiripicchio, A. Organometallics 1996, 15, 4274.
14. (a) Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
15. (b) Hoffmann, R.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179, 2872.
16. See for example: Miguel, D.; Riera, V.; Miguel, J. A.; Gómez, M.; Soláns, X. Organometallics 1991, 10, 1683.
17. (a) Galindo, A.; Gutiérrez-Puebla, E.; Monge A.; Pastor, A.; Pizzano, A.; Ruiz, C.; Sánchez, L.; Carmona, E. Inorg. Chem. 1993, 32, 5569.
18. (b) Carmona, E.; Gutiérrez-Puebla, E.; Monge, A.; Pérez, P.; Sanchez, L. Inorg. Chem. 1989, 28, 2120.
19. (c) Galindo, A.; Mealli, C.; Cuyás, J.; Miguel, D.; Riera, V.; Pérez-Martinez, J.; Bois, C.; Jeannin, Y. Organometallics 1996, 15, 2735.
20. Churchill, M. R.; Youngs, W. J. Inorg. Chem. 1979, 18, 2454.
21. (a) Similar data have been reported for analogous tungsten ketenyl complexes: Birdwhistell, K. R.; Tonker, T. L.; Templeton, J. L. J. Am. Chem. Soc. 1985, 107, 4474 and references therein.
22. (b) An analogous intermediate has been postulated in the formation of related ketenyl complexes also generated by the reaction of tungsten carbonyl-carbyne complexes with dithiocarbamate ligands (see ref 9a).
23. (c) Hill, A. F.; Malget, J. M.; White, A. J. P.; Williams, D. J. J. Chem. Soc., Chem. Commun. 1996, 721.
24. (d) Brower, D. C.; Stoll, M.; Templeton, J. L. Organometallics 1989, 8, 2786.
25. (e) Mayr, A.; Chang, R. T.; Lee, T. Y.; Cheung, O. K.; Kjelsberg, M. A.; McDermott, G. A.; Engen, D. V. J. Organomet. Chem. 1994, 479, 47.
26. Haiduc, I.; Sowerby, D. B.; Lu, S. F. Polyhedron 1995, 14, 3389.
27. See for example: (a) Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; García-Granda, S. Orgomometallics 1994, 13, 4667.
28. (b) Barrado, G.; Li, J.; Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; Bois, C.; Jeannin, Y. Organometallics 1994, 13, 2330.
29. (c) Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; García-Granda, S. Organometallics 1994, 13, 1336.
30. (d) Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; García-Granda, S. Organometallics 1993, 12, 2888.
31. (e) Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; García-Granda, S. Organometallics 1993, 12, 1394.
32. (f) Miguel, D.; Pérez-Martínez, J. A.; Riera, V.; García-Granda, S. Angew. Chem. 1992, 31, 76.
33. Galindo, A.; Mealli, C. Inorg. Chem. 1996, 35, 2406.
34. See for example: Albright, T. A.; Burdett, J. K.; Whangbo, M.-H. Orbital Interactions in Chemistry; Wiley: New York, 1985.
35. Neutral formalism avoids the oxidation state assignment, see for example: (a) Wilker, C. N.; Hoffmann, R.; Eisenstein, O. Nouv. J. Chim. 1983, 7, 535.
36. (b) Hoffmann, R.; Wilker, C. N.; Eisenstein, O. J. Am. Chem. Soc. 1982, 104, 632.
37. (a) Brower, D. C.; Templeton, J. L.; Mingos, D. M. P. J. Am. Chem. Soc. 1987, 109, 5203.
38. (b) Kostic, N. M.; Fenske, R. F. Organometallics 1982, 1, 489.
39. (c) Kostic, N. M.; Fenske, R. F. J. Am. Chem. Soc. 1981, 103, 4677.
40. See for example: Templeton, J. L.; Winston, P. B.; Ward, B. C. J. Am. Chem. Soc. 1981, 103, 7713.
41. Nugent, W. A.; Mayer, J. M. Metal Ligand Multiple Bonds; Wiley: New York, 1988.
42. See for example: (a) Hall, K. A.; Mayer, J. M. J. Am. Chem. Soc. 1992, 114, 10402.
43. (b) Su, F.-M.; Bryan, J. C.; Jang, S.; Mayer, J. M. Polyhedron 1989, 8, 1261.
44. (c) Templeton, J. L.; Ward, B. C.; Chen, G. J.-J.; McDonald, J. W.; Newton, W. E. Inorg. Chem. 1981, 20, 1248.
45. See for example: (a) Clark, G. R.; Nielson, A. J.; Rickard, C. E. F. J. Chem. Soc., Dalton Trans. 1995, 1907.
46. (b) Clark, G. R.; Glenny, M. W.; Nielson, A. J.; Rickard, C. E. F. J. Chem. Soc., Dalton Trans. 1996, 1147.
47. (c) Montilla, F.; Galindo, A.; Carmona, E. Unpublished results.
48. See for example: Atagi, L. M.; Mayer, J. M. Organometallics 1994, 13, 4794 and references therein.
49. Hyde, J.; Venkatasubramanian, K.; Zubieta, J. Inorg. Chem. 1978, 17, 414.
50. Tatsumisago, M.; Matsubayashi, G.; Tanaka, T.; Nishigaki, S.; Nakatsu, K. J. Chem. Soc, Dalton Trans. 1982, 121.
51. Carmona, E.; Galindo, A.; Gutiérrez-Puebla, E.; Monge, A.; Puerta, C. Inorg. Chem. 1986, 25, 3804.
52. Carmona, E.; Galindo, A.; Guille-Photin, C.; Laï, R.; Monge, A.; Ruiz, C.; Sánchez, L. Inorg. Chem. 1988, 27, 488.
53. (a) Walker, N.; Stuart, D. Acto Crystallogr., Sect. A 1983, 39, 158.
54. (b) Ugozzoli, F. Comput. Chem. 1987, 11, 109.
55. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974, Vol IV.
56. Sheldrick, G. M. SHELX-7, Program for crystal structure determination; University of Cambridge: Cambridge, England, 1976; SHELXS-86, Program for the solution of crystal structures; University of Göttingen: Göttingen, The Netherlands, 1986.
57. Sheldrick, G. M. SHELX-7, Program for crystal structure determination; University of Cambridge: Cambridge, England, 1976; SHELXS-86, Program for the solution of crystal structures; University of Göttingen: Göttingen, The Netherlands, 1986.
58. Alvarez, S. Tables of Parameters for Extended Hückel Calculations; Departamento de Química Inorgánica, Universidad de Barcelona: Barcelona, Spain, 1989.
59. Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67, 399.