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0009254419
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A fluid of perfectly aligned HGO molecules can be made thermodynamically equivalent to a fluid of hard spheres by appropriate scaling along the direction of alignment [see
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A fluid of perfectly aligned HGO molecules can be made thermodynamically equivalent to a fluid of hard spheres by appropriate scaling along the direction of alignment [see J. L. Lebowitz and J. W. Perram, Mol. Phys. 50, 1207 (1983), who discussed this point for hard ellipsoids of revolution]. Since hard spheres do not exhibit phases intermediate between the fluid and the three-dimensional crystal, a smectic phase should not exist in the HGO system.
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Lebowitz, J.L.1
Perram, J.W.2
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26
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22244445871
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′=5 has been calculated previously (Ref. 6) using a perturbative theory related to the one presented here but slightly more sophisticated (WCA splitting of the potential, introduction of an approximate reference radial distribution function, and full minimization of the one-molecule distribution function). This theory, however, is not suitable to describe the smectic phase.
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′=5 has been calculated previously (Ref. 6) using a perturbative theory related to the one presented here but slightly more sophisticated (WCA splitting of the potential, introduction of an approximate reference radial distribution function, and full minimization of the one-molecule distribution function). This theory, however, is not suitable to describe the smectic phase.
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