N-H Activation. 1. Oxidative Addition of Ammonia to Iridium(I). Isolation, Structural Characterization, and Reactivity of Amidoiridium Hydrides

Inorganic Chemistry

Volumn 26, Issue 7, 1987, Pages 971-973

  Casalnuovo, Albert L ^a   Calabrese, Joseph C ^a   Milstein, David ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000161196     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00254a001     Document Type: Article

References (12)

1. Armor, J. N. Inorg. Chem. 1978, 17, 203.
2. Armor, J. N. Jnorg. Chem. 1978, 17, 213.
3. Hillhouse, G. L.; Bercaw, J. E. J. Am. Chem. Soc. 1984, 106, 5472.
4. Suss-Fink, G. Z.; Naturforsch, B. Inorg. Chem., Org. Chem. 1980, 35B, 454. Sappa E.; Milone, L. J. Organomet. Chem. 1973, 61, 383. Lin, Y.; Mayr, A.; Knobler, C. B.; Kaesz, H. D. J. Organomet. Chem. 1984, 272, 207. Johnson, B. F. G.; Lewis, J.; Odiaka, T.; Raithby, P. R. J. Organomet. Chem. 1981, 216, C56. Johnson, B. F. G.; Lewis, J. J. Chem. Soc., Dalton Trans. 1977. 1328.
5. Hadden, D.: Roundhill, D. M.; Fultz, W. C.; Rheingold, A. L. J. Am. Chem. Soc. 1984, 106, 5014. Roundhill, D. M. Inorg. Chem. 1970, 9, 254–258. Yamamoto, T.; Sano, K.; Yamamoto A. Chem. Lett. 1982, 907–910. Nelson, J. H.; Schmidt, D. L.; Henry, R. A.; Moore, D. W.; Jonassen, H. B. Inorg. Chem. 1970, 9, 2678–2681. Fornies, J.; Green, M.; Spencer, J. L.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1977, 1006–1009. Goel, R. A.; Srivastava, R. C. J. Organomet. Chem. 1983, 244, 303–310. Rauchfuss, T. B.; Roundhill, D. M. J. Am. Chem. Soc. 1974, 96, 3098–3105. Mague, J. T. Inorg. Chem. 1972, 11, 2558-2560.
6. 3 complexes have been structurally characterized. Kretschmer, M.; Heck, L. Z. Anorg. Allg. Chem. 1982, 490, 215. Schaefer, W. P. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1983, 39, 1610. Rotzwinger, F. P.; Marty, W. Inorg. Chem. 1983, 22, 3593. Clegg, W.; Sykes, A. G. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1984, 40, 1820. Curtis, N. J.; Hagen, K. S.; Sargeson, A. M. J. Chem. Soc. Chem. Commun. 1984, 1571.
7. A similar M—N distance at 2.09 (2) A was found for the related complex cis-Pt(PEt3)2(NPh2)Cl: Eadie, D. T.; Pidcock, A.; Stobart, S. R.; Brennan, E. T.; Cameron, S. T. Inorg. Chim. Acta 1982, 65, LI 11.
8. Nujol mull on polyethylene plates. See: Schramm, K. D.; Tulip, T. H.; Ibers, J. A. Inorg. Chem. 1980, 19, 3183.
9. Bradley, D. C.; Chisholm, M. H. Acc. Chem. Res. 1976, 9, 273.
10. For a discussion of insertion behavior of metal amides see: Lappert, M. F.; Power, P. P.; Sanger, A. R.; Srivastava, R. C. Metal and Metalloid Amides: Ellis Horwood: Chickester. U. K., 1980.
11. Halpern, J.; Wong, C. S. J. Chem. Soc. Chem. Commun. 1973, 629.
12. Milstein, D. J. Am. Chem. Soc. 1982,104, 5227. Milstein, D. Acc. Chem. Res. 1984. 17. 221.