Heterosupramolecular Chemistry: Self-Assembly of an Electron Donor (TiO2 Nanocrystallite) - Acceptor (Viologen) Complex

Chemistry of Materials

Volumn 9, Issue 8, 1997, Pages 1765-1772

  Cusack, Lucy ^a   Marguerettaz, Xavier ^a   Nagaraja Rao, S ^a   Wenger, John ^a   Fitzmaurice, Donald ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000158753     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm9605173     Document Type: Article

References (51)

1. Marguerettaz, X.; O'Neill, R.; Fitzmaurice, D. J. Am. Chem. Soc. 1994, 116, 2628
2. (a) Lehn, J.-M. Supramolecular Chemistry; VCH: New York, 1995.
3. (b) Balzani, V.; Scandola, F. Supramolecular Photochemistry; Ellis Horwood: New York, 1991; Chapter 3.
4. Marguerettaz, X.; Fitzmaurice, D. J. Am. Chem. Soc. 1994, 116, 5017.
5. Marguerettaz, X.; Redmond, G.; Rao, S. N.; Fitzmaurice, D. SPIE Proc. Ser. 1994, 2255, 793.
6. Marguerettaz, X.; Redmond, G.; Rao, S. N.; Fitzmaurice, D. Chem. Eur. J. 1996, 2, 420.
7. (a) Philp, D.; Stoddart, J. F. Synlett 1991, 445.
8. (b) Lindsey, J. S. New J. Chem. 1991, 15, 153.
9. (c) Whitesides, G. M.; Mathias, J. P.; Seto, C. T. Science 1991, 254, 1312.
10. Cusack, L.; Rao, S. N.; Wenger, J.; Fitzmaurice, D. Chem. Mater. 1997, 9, 624.
11. Cusack, L.; Rao, S. N.; Fitzmaurice, D. Angew. Chem., Int. Ed. Engl. 1997, 36, 848.
12. Brienne, M.-J.; Gabard, J.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1989, 1868.
13. (a) Feibush, B.; Fiueroa, A.; Charles, R.; Onan, K.; Feibush, P.; Karger, B. J. Am. Chem. Soc. 1986, 108, 3310.
14. (b) Feibush, B.; Saha, M.; Onan, K.; Karger, B.; Giese, R. J. Am. Chem. Soc. 1987, 109, 7531.
15. (c) Hamilton, A.; Van Engen, D. J. Am. Chem. Soc. 1987, 109, 5035.
16. (d) Bisson, A.; Carver, F.; Hunter, C.; Waltho, J. J. Am. Chem. Soc. 1994, 116, 10292.
17. Bellamy, L. J. The Infrared Spectra of Complex Molecules; Mathuen: London, 1954.
18. (a) Tsuboi, M. Appl. Spectrosc. Rev. 1969, 3, 45.
19. (b) Susi, H.; Ard, J. Spectrochim. Acta 1971, 27A, 1549.
20. (a) Hamlin, R.; Lord, R.; Rich, A. Science 1965, 148, 1734.
21. (b) Kyogoku, Y.; Lord, R.; Rich, A. Proc. Natl. Acad. Sci, U.S.A, 1967, 57, 250.
22. (c) Kyogoku, Y.; Lord, R.; Rich, A. J. Am. Chem. Soc. 1967, 89, 496.
23. (d) Kyogoku, Y.; Lord, R.; Rich, A. Biochim. Biophys. Acta 1969, 179, 10.
24. (e) Zundel, G.; Lubos, W.; Kolkenbeck, K. Can. J. Chem. 1971, 49, 3795.
25. Pimentel, G.; McClellan, A. The Hydrogen Bond; Freeman: San Francisco, 1956.
26. Kotov, N.; Meldrum, F.; Fendler, J. J. Phys. Chem. 1994, 98, 8827.
27. This calculation assumed complete conversion of the precursors and that the average crystallite diameter was 22 ± 2 Ä.
28. Serpone, N.; Lawless, D.; Khairutdinov, R. J. Phys. Chem. 1995, 99, 16646.
29. Rizza, R.; Merrins, A.; Fitzmaurice, D., manuscript in preparation.
30. (a) Henglein, A. Ber. Bunsen-Ges. Phys. Chem. 1982, 86, 246.
31. (b) Duonghong, D.; Ramsden, J.; Grätzel, M. J. Am. Chem. Soc. 1982, 104, 2977.
32. (c) Kolle, U.; Moser, J.; Grätzel, M. Inorg. Chem. 1985, 24, 2253.
33. (d) Rothenberger, G.; Moser, J.; Grätzel, M.; Serpone, N.; Sharma, D. J. Am. Chem. Soc. 1985, 107, 8054.
34. There is general agreement that the spectrum of trapped holes does not extend to wavelengths longer than about 450 nm: (a) Bahnemann, D.; Henglein, A.; Lilie, J.; Spanhel, L. J. Phys. Chem. 1984, 88, 709. (b) Micic, O.; Zhang, Y.; Cromack, R.; Trifunac, A.; Thurnauer, M. J. Phys. Chem. 1993, 97, 7277.
35. There is general agreement that the spectrum of trapped holes does not extend to wavelengths longer than about 450 nm: (a) Bahnemann, D.; Henglein, A.; Lilie, J.; Spanhel, L. J. Phys. Chem. 1984, 88, 709. (b) Micic, O.; Zhang, Y.; Cromack, R.; Trifunac, A.; Thurnauer, M. J. Phys. Chem. 1993, 97, 7277.
36. (a) Kok, B.; Rurainski, H.; Owens, O. Biochem. Biophys. Acta 1965, 109, 347.
37. (b) Trudinger, P. Ananl. Biochem. 1970, 36, 222.
38. (c) Wantanabe, T.; Honda, K. J. Phys. Chem. 1982, 86, 2617.
39. Frei, H.; Fitzmaurice, D.; Grätzel, M. Langmuir 1990, 6, 198.
40. 2-(I+IV) will be discussed here and supported by detailed NMR studies.
41. For example ethanol has been shown to act as an efficient hole scavenger in a number of studies: Semiconductor Electrodes; Finklea, H., Ed.; Elsevier: New York, 1988; p 113.
42. (a) Sessler, J.; Wang, B.; Harriman, A. J. Am. Chem. Soc. 1995, 117, 704 and references therein.
43. (b) Chidsey, C. Science 1991, 251, 919.
44. (b) Finklea, H.; Hanshew, D. J. Am. Chem. Soc. 1992, 114, 3173.
45. (c) Cleland, G.; Horrocks, B.; Houlton, A. J. Chem. Soc., Faraday Trans. 1995, 91, 4001.
46. Cusack, L.; Fitzmaurice, D., manuscript in preparation.
47. (a) Murray, C.; Kagan, C.; Bawendi, M. Science 1996, 270, 1335.
48. (b) Mirkin, B.; Letsinger, R.; Mucic, R.; Storhoff, J. Nature 1996, 382, 607.
49. (c) Alivisatos, P.; Johnson, K.; Xiaongang Peng; Wilson, T.; Loweth, C.; Bruchez, M.; Schultz, P. Nature 1996, 382, 609.
50. (d) Kamat, P; Bedja, I.; Vonodgopal, K. Fine Particle Science and Technology; Nato ASI Ser. 3, 1996, 12, 303.
51. Fitzmaurice, D.; Eschle, M.; Frei, H.; Moser, J. J. Phys. Chem. 1993, 97, 3806.