Pyramidal Inversion at Phosphorus Facilitated by the Presence of Proximate Lewis Acids. Coordination Chemistry of Group 13 Elements with the Macrocyclic Bis(amidophosphine) Ligand [P2N2] ([P2N2] = [PhP(CH2SiMe2NSiMe2CH2) 2PPh])

Inorganic Chemistry

Volumn 37, Issue 26, 1998, Pages 6928-6934

  Fryzuk, Michael D ^a   Giesbrecht, Garth R ^a   Rettig, Steven J ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000156675     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9805978     Document Type: Article

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46. w was 0.029 with conventional R = 0.029. GOF = 1.73. Selected bond length for 3: CI(1)-AI(1) = 2.197 Å; P(1)-Al(1) = 2.481(1) Å: P(2)-Al(1) = 2.465(1) Å; N(1)-A1(1) = 1.886(3) Å; N(2) - Al(1) = 1.909(3) Å.