Observing and modelling energetically close α- And β-carbon-hydrogen agostic interactions in an isopropyl tris(pyrazolyl)boratoniobium complex

Chemical Communications

Volumn , Issue 18, 1998, Pages 2011-2012

  Jaffart, Joëlle ^a   Mathieu, René ^a   Etienne, Michel ^a   McGrady, John E ^b   Eisenstein, Odile ^b   Maseras, Feliu ^b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b UNIV MONTPELLIER   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000155768     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a805993d     Document Type: Article

References (8)

1. For a review on agostic interactions, see: M. Brookhart, M. L. H. Green and L.-L. Wong, Prog. Inorg. Chem., 1988, 36, 1.
2. 6 centers, see: (a) W. E. Piers and J. E. Bercaw, J. Am. Chem. Soc., 1990, 112, 9406;
3. (b) H. Krauledat and H.-H. Brintzinger, Angew. Chem., Int. Ed Engl., 1990, 29, 1412;
4. (c) N. Barta, B. A. Kirk and J. R. Stille, J. Am. Chem. Soc., 1994, 116, 8912;
5. (d) R. H. Grubbs and G. W. Coates, Acc. Chem. Res., 1996, 29, 85
6. 6 centers, see: M. J. Tanner, M. Brookhart and J. M. DeSimone, J. Am. Chem. Soc., 1997, 119, 7617.
7. For multiple agostic interactions, see: (a) A. D. Poole, D. N. Williams, A. M. Kenwright, V. C. Gibson, D. C. R. Hockless and P. A. O'Neil, Organometallics, 1993, 12, 2549;
8. (b) K. H. den Hann, L. J. de Boer, J. H. Teuben, A. L. Spek, B. Kojic-Prodic, G. H. Hays and R. Huis, Organometallics 1986, 5, 1726.