Synthesis, molecular structure and reactions of stable square-planar 16-electron ruthenium(0) complexes: Trans-[RuCl(NO)(PR3)2]

Chemische Berichte

Volumn 129, Issue 9, 1996, Pages 1007-1013

  Flügel, Ruth ^a   Windmüller, Bettina ^a   Gevert, Olaf ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Dioxygenruthenium complexes; Nitrosyl complexes; Oxidative addition reactions; Ruthenlum(0) complexes; Sulfur dioxide, metal assisted oxidation of

Indexed keywords

EID: 0000154566     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290906     Document Type: Article

References (48)

1. F. H. Jardine, P. S. Sheridan in Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty) Vol. 4, Pergamon, Oxford, 1987. chapter 48.4.
2. P. L. Bogdan, E. Weitz. J. Am. Chem. Soc. 1989, 111, 3163-3167.
3. [3a] Werner, R. Werner, J. Organomet. Chem. 1981, 209, C60-C64.
4. [3b] J. Gotzig, R. Werner, H. Werner, J. Organomet. Chem. 1985, 290, 99-114.
5. [4a] H. Kletzin, H. Werner, Angew. Chem. 1983, 95, 916-917;
6. Angew. Chem. Int. Ed Engl. 1983, 22, 873-874.
7. [4b] H. Werner, H. Kletzin, K. Roder, J. Organomet. Chem. 1988, 355, 401-417.
8. M. Ogasawara, S. A. Macgregor, W. E. Streib, K. Folting, O. Eisenstein, K. G. Caulton, J. Am. Chem. Soc. 1995, 117, 8869-8870.
9. L. Cronin, M. C. Nicasio, R. N. Perutz, R. G. Peters, D. M. Roddick, M. K. Whittlesey, J. Am. Chem. Soc. 1995, 117, 10047-10050.
10. M. A. A. F. de C. T. Carrondo, B. N. Chaudret, D. J. ColeHamilton, A. C. Skapski, G. Wilkinson, J. Chem. Soc., Chem. Commun. 1978, 463-464.
11. [8a] H. Werner, A. Michenfelder, M. Schulz, Angew. Chem. 1991, 103, 616-617;
12. Angew. Chem. Int. Ed. Engl. 1991, 30, 596-597.
13. [8b] H. Werner, R. Flügel, B. Windmüller, A. Michenfelder, J. Wolf. Organomelollies 1995, 14, 612-618.
14. [9a] M. H. B. Stiddard, R. E. Townsend, J. Chem. Soc., Chem. Commun. 1969, 1372.
15. 2] see: R. D. Wilson, J. A. Ibers, Inorg. Chem. 1978, 17, 2134-2138.
16. J. Clemens, M. Green, F. G. A. Stone, J. Chem. Soc., Dalton Trans. 1973, 375-380.
17. [11a] C. Busetto, A. D'Alfonso, F. Maspero, G. Perego, A. Zazzetta, J. Chem. Soc., Dalton Trans. 1977, 1828-1834.
18. [11b] D. L. Thorn, T. H. Tulip, J. A. Ibers, J. Chem. Soc., Dalton Trans. 1979, 2022-2025.
19. [11c] L. Dahlenburg, A. Yardimicoglu, J. Organomet. Chem. 1985, 291, 371-386.
20. [11d] W. A. Schenk, J. Leißner, C. Burschka, Angew. Chem. 1984, 96, 787-788:
21. Angew. Chem. Int. Ed. Engl. 1984, 23, 806-807.
22. K. Wang, G. P. Rosini, S. P. Nolan, A. S. Goldman, J. Am. Chem. Soc. 1995, 117, 5082-5088.
23. A. F. Hill in Comprehensive Organometallic Chemistry II (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson) Vol. 7, Pergamon, Oxford, 1995, chapter 6.1.
24. [14a] A. F. Hill, W. R. Roper, J. M. Waters, A. H. Wright. J. Am. Chem. Soc. 1983, 105, 5939-5940.
25. [14b] A. K. Burell, G. R. Clark, C. E. F. Rickard, W. R. Roper, A. H. Wright, J. Chem. Soc., Dalton Trans. 1991, 609-614.
26. [14b] P. J. Brothers, W. R. Roper, Chem. Rev. 1988, 88, 1293-1326.
27. H. Werner, A. Höhn, M. Dziallas, Angew. Chem. 1986, 98, 1112-1114;
28. Angew. Chem. Int. Ed. Engl. 1986, 25, 1090-1092.
29. H. Werner, M. Esteruelas, H. Otto, Organometallics 1986, 5, 2295-2299.
30. B. Giovannitti, O. Gandolfi, M. Ghedini, G. Dolcelti, J. Organomet. Chem. 1977, 129, 207-214.
31. J. A. McGinnety, J. A. Ibers, J. Chem. Soc., Chem. Commun. 1968, 235-237.
32. [19a] M. A. Gallop, W. R. Roper, Adv. Organomet. Chem. 1986, 25, 121-198.
33. [19b] W. R. Roper, J. Orgonomet. Chem. 1986, 300, 167-190.
34. [20a] J. S. Valentine, Chem. Rev. 1973, 73, 235-245.
35. [20b] L. Vaska, Acc. Chem. Res. 1976, 9, 175-183.
36. [20c] O. Hevke, G. Beuter, I.-P. Lorenz, J. Organomet. Chem. 1992, 440, 197-205.
37. H. A. O. Hill, D. G. Tew in Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty) Vol. 2, Pergamon, Oxord, 1987, chapter 15.2.
38. A. F. Wells, Structural Inorganic Chemistry, 5th edition, Clarendon Press, Oxford, 1984, chapter 16.
39. J. Reed, S. L. Soled, R. Eisenberg, Inorg. Chem. 1974, 12, 3001-3005.
40. [24a] A. C. Skapski, F. A. Stephens, J. Chem. Soc., Dalton Trans. 1974, 390-395.
41. [24b] G. R. Clark, C, E. L. Headford, W. R. Roper, L. J. Wright, V. P. D. Yap, Inorg. Chim. Acta 1994, 220, 261-212.
42. 2 (X = Cl, OAc, acac) see:[25a] H. Werner, J. Organomet. Chem. 1994, 475, 45-55.
43. [25b] H. Werner, M. Schäfer, J. Wolf, K. Peters, H. G. von Schnering, Angew. Chem. 1995, 107, 213-215;
44. Angew. Chem. Int. Ed. Engl. 1995, 34, 191-194.
45. [25c] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, L. Rodriguez, P. Steinert, H. Werner, Organometallics 1996, 15, in Dress.
46. J. J. Levison, S. D. Robinson, J. Chem. Soc. 1970, 2947-2954.
47. F. Kukla, Dissertation, Universität Würzburg, in preparation.
48. Futher details of the crystal structure investigations are available on request from the Fachintbrmationszentrum Karlsruhe, Gesellschaft für wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen, on quoting the depository numbers CSD-59296 (2) and -405160 (13), the names of the authors, and the journal citation.